• 专利标题:   Composite nano filler composition comprises graphene oxide, p-phenylenediamine, and acidified multi-walled carbon nanotube, prepared by e.g. mixing multi-walled carbon nanotube with concentrated sulfuric acid and concentrated nitric acid.
  • 专利号:   CN110713743-A
  • 发明人:   YANG B, LI M, ZHU Z, WEN F, ZHANG S, DI W, LI S
  • 专利权人:   GUANGZHOU SPECIAL PRESSURE EQUIP INSPECT
  • 国际专利分类:   C09D163/00, C09D005/08, C09D005/24
  • 专利详细信息:   CN110713743-A 21 Jan 2020 C09D-005/24 202014 Pages: 12 Chinese
  • 申请详细信息:   CN110713743-A CN10985325 16 Oct 2019
  • 优先权号:   CN10985325

▎ 摘  要

NOVELTY - Composite nano filler composition comprises graphene oxide, p-phenylenediamine, and acidified multi-walled carbon nanotube in a mass ratio of 1:7-10:2-3. USE - The graphene conductive anticorrosive coating is useful for grounding grids (claimed). ADVANTAGE - The graphene coating has improved conductivity and corrosion resistance, acid and alkali resistance properties, improved hardness and durability, and prolonged coating life. DETAILED DESCRIPTION - INDEPENDENT CLAIMS are also included for: (1) the preparation of composite nano filler comprising adding multi-walled carbon nanotube to a mixture of concentrated sulfuric acid and concentrated nitric acid, heating to reflux to obtain acidified multi-walled carbon nanotube, mixing graphene oxide and p-phenylenediamine in a mass ratio of 1:7-10, adding ammonia water, heating to reflux to obtain reduced graphene oxide grafted with p-phenylenediamine, mixing reduced graphene oxide grafted with p-phenylenediamine and acidified multi-walled carbon nanotube, heating to reflux, and vacuum drying to obtain graphene oxide-p-phenylenediamine-carbon nanotube composite; and (2) a graphene conductive anticorrosive coating, prepared by mixing and uniformly stirring 40-60 wt.% epoxy resin, 0.1-1 wt.% dispersant, 5-15 wt.% solvent, 10-30 wt.% filler, 1-5 wt.% coupling agent, 15-25 wt.% curing agent, and 0.1-2 wt.% composite nano-filler.