• 专利标题:   Concurrently forming ammonia and solid carbon products e.g. graphene, includes reacting carbon oxide, nitrogen and reducing agent in presence of catalyst to form solid carbon entrained in tail gas mixture, and recovering ammonia.
  • 专利号:   WO2014011206-A1, US2015147259-A1, CN104619640-A, JP2015527968-W, MX2015000580-A1, JP6025979-B2, US9598286-B2, CN104619640-B, US2017190578-A1, CN107215882-A, US10358346-B2
  • 发明人:   NOYES D B
  • 专利权人:   SEERSTONE LLC, NOYES D B, SEERSTONE LLC, SEERSTONE LLC
  • 国际专利分类:   B82B001/00, B82B003/00, C01B031/02, C01C001/00, C01C001/04, B82Y040/00, C01C001/02, B82Y030/00, D01F009/12, C01B032/00, C01B032/162, C01B005/00, C01B032/15, C01B032/16, C01C001/10, C01B032/05
  • 专利详细信息:   WO2014011206-A1 16 Jan 2014 C01C-001/00 201410 Pages: 32 English
  • 申请详细信息:   WO2014011206-A1 WOUS000078 15 Mar 2013
  • 优先权号:   US671464P, US14414364, US463950

▎ 摘  要

NOVELTY - Concurrently forming (M1) ammonia and solid carbon products, comprises: reacting at least one carbon oxide, nitrogen, and at least one reducing agent at preselected temperature and a preselected pressure in the presence of a catalyst to form solid carbon entrained in a tail gas mixture comprising water, ammonia, and unreacted gases; separating the entrained solid carbon from the tail gas mixture; recovering water from the tail gas mixture; and recovering ammonia from the tail gas mixture. USE - The method is useful for concurrently forming ammonia, and solid carbon products (claimed) including graphite, graphene, carbon black, fibrous carbon, buckminsterfullerene, single-wall carbon nanotubes, multi-wall carbon nanotubes, carbon platelets, or nanodiamond. ADVANTAGE - The method: minimizes or eliminates carbon dioxide emissions; conserves reaction gases and minimizes worker and environmental exposure to the reaction gases; and does not require a ceramic or metallic support for the catalyst, and thus simplifies the setup of the reactor and reduces the costs. DETAILED DESCRIPTION - INDEPENDENT CLAIMS are also included for: (1) producing (M2) ammonia and solid carbon products, comprising: heating a first gas stream to a predetermined reaction temperature to form a first heated gas stream, where the first gas stream comprises at least one carbon oxide and nitrogen; heating a second gas stream to the predetermined reaction temperature to form a second heated gas stream, where the second gas stream comprises at least one reducing agent; mixing the first heated gas stream with the second heated gas stream; reacting the nitrogen, the at least one carbon oxide, and the at least one reducing agent in the presence of a catalyst to form a solid carbon product entrained in a tail gas mixture comprising steam, ammonia, and a residual gas mixture; separating at least a portion of the entrained solid carbon product from the tail gas mixture; and separating the tail gas mixture to form a water stream, an ammonia product stream, and a residual gas stream; and (2) a system (100) for forming ammonia and solid carbon products from a gaseous source (102) containing at least one carbon oxide and nitrogen (104), comprising: a mixing means for mixing the gaseous source with at least one reducing agent (106); a reactor means for reacting at least a portion of the gaseous source with the at least one reducing agent in the presence of a catalyst to produce the solid carbon products and a tail gas mixture comprising water and ammonia; and a solid separation means for separating the solid carbon products from the tail gas mixture. DESCRIPTION OF DRAWING(S) - The figure illustrates a system for forming ammonia and solid carbon products. System (100) Source gas stream (102) Nitrogen (104) Reducing agent (106) Converter (112)