• 专利标题:   Preparing modified graphene oxide for preparing polyurethane/modified graphene nanocomposite emulsion used in coatings, involves adding graphene oxide dispersion to stirrer, and adding polyethyleneimine under high-speed stirring.
  • 专利号:   CN111087651-A
  • 发明人:   ZHANG S, TIAN D, LU J, BAI H, WANG W, DONG W
  • 专利权人:   UNIV JIANGNAN
  • 国际专利分类:   C08J003/03, C08J005/18, C08J009/00, C08K003/04, C08K009/04, C08L075/04, C09D011/03, C09D011/38, C09D175/04, C09D007/62, C09J011/04, C09J175/04
  • 专利详细信息:   CN111087651-A 01 May 2020 C08K-009/04 202043 Pages: 13 Chinese
  • 申请详细信息:   CN111087651-A CN11415130 31 Dec 2019
  • 优先权号:   CN11415130

▎ 摘  要

NOVELTY - Preparing modified graphene oxide involves adding the graphene oxide dispersion to a stirrer, adding polyethyleneimine under high-speed stirring, then adjusting the pH to 14 and stirring to obtain the mixed solution, and then adjusting the pH of the mixed solution to 5.5, adding 1-ethyl-(3-dimethylaminopropyl) carbodiimide hydrochloride and N-hydroxysuccinimide compound, and sonicating in a water bath to get a mixture. The mixture is stirred in an ice water bath, and then subjected to centrifugal washing to obtain a solid i.e. modified graphene oxide. USE - Method for preparing modified graphene oxide for preparing a waterborne polyurethane/modified graphene nanocomposite emulsion used in field of coatings, adhesives, inks, surface treatment agents, elastomers, foam materials or functional films (all claimed). ADVANTAGE - The method improves the dispersibility of graphene in aqueous polyurethane by greatly improving the conductivity of the composite emulsion. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is included for a method for preparing a waterborne polyurethane/modified graphene nanocomposite emulsion, which involves dropping an aqueous polyurethane prepolymer into a modified graphene oxide dispersion.