• 专利标题:   Preparation dopamine-based gallium-graphene oxide composite coating on zinc surface comprises e.g. preparing gallium-loaded coating sample marked with zinc/gallium and polydopamine film and soaking in graphene oxide solution.
  • 专利号:   CN111321403-A
  • 发明人:   HUANG Y, ZHANG X, QIAO H, MA L, WANG B
  • 专利权人:   UNIV HEBEI NORTH
  • 国际专利分类:   A61L027/30, A61L027/54, A61L027/58, C23C022/60, C23C026/00
  • 专利详细信息:   CN111321403-A 23 Jun 2020 C23C-026/00 202063 Pages: 6 Chinese
  • 申请详细信息:   CN111321403-A CN10162811 10 Mar 2020
  • 优先权号:   CN10162811

▎ 摘  要

NOVELTY - Preparation dopamine-based gallium-graphene oxide composite coating on zinc surface comprises (i) sequentially pretreating the surface of the zinc substrate and then subjecting to alkali heat treatment, (ii) soaking the alkali-heat-treated zinc substrate in the gallium nitrate solution to obtain gallium-loaded coating sample marked with zinc/gallium, (iii) dissolving dopamine hydrochloride in trihydroxyaminomethane solution, making the concentration of the solution to 1-3 g/l, adjusting pH to 8.5, magnetically stirring under aerobic room temperature conditions and protection of light, soaking for 24 hours to form polydopamine film, soaking the obtained gallium-bearing zinc sheet in the dopamine solution to obtain gallium-dopamine coated samples marked with zinc/gallium/ polydopamine, and (iv) adding the gallium-dopamine coating sample at 37 degrees C into 1-6 g/l graphene oxide solution, and soaking for 24 hours to obtain final product. USE - The method is useful for preparing dopamine-based gallium-graphene oxide composite coating on zinc surface. ADVANTAGE - The method has improved comprehensive performance, synergistically high efficiency and antibacterial effect and reduced infection of zinc in human body; slows down the degradation rate of zinc flakes and reduces the degradation rate of zinc.