• 专利标题:   Low-heat release low-smoke high-flame retardant epoxy resin material comprises epoxy resin, halogen-free essential flame retardant (9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide flame retardant), and synergistic flame retardant (melamine flame retardants) and curing agent.
  • 专利号:   CN113667277-A
  • 发明人:   CHEN Y, DONG L, LI P, LIN Z, XU X, XU B, YE W, FU C, XIAO X
  • 专利权人:   SHANGHAI CHEM IND RES INST CO LTD
  • 国际专利分类:   C08K003/34, C08K005/52, C08K005/3492, C08K005/5313, C08K003/08, C08K003/04, C08K009/12, C08L063/02
  • 专利详细信息:   CN113667277-A 19 Nov 2021 C08L-063/02 202204 Chinese
  • 申请详细信息:   CN113667277-A CN10980180 25 Aug 2021
  • 优先权号:   CN10980180

▎ 摘  要

NOVELTY - Low-heat release low-smoke high-flame retardant epoxy resin material comprises 40-80 pts. wt. epoxy resin, 0.1-20 pts. wt. halogen-free essential flame retardant, 0.1-20 pts. wt. curing agent, where halogen-free intrinsic flame retardants is 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide flame retardant and synergistic flame retardant is melamine flame retardants or piperazine pyrophosphate flame retardants. USE - Used as low-heat release low-smoke high-flame retardant epoxy resin material. ADVANTAGE - The epoxy resin material: has high thermal stability, excellent mechanical properties; does not contain halogen; does not migrate; overcomes the defects of easy combustion; has high heat release and high smoke emission compared with traditional epoxy resin materials; can reach the V0 level; and has reduced pHRR of 27.9%. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is also included for preparing low-heat release low-smoke high-flame retardant epoxy resin material comprising (1) mixing the epoxy resin and the 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide flame retardant, then stirring and reacting, (2) adding the synergistic flame retardant, continuing the reaction and then adding the curing agent for the curing reaction to obtain final product.