• 专利标题:   Preparation of polypyrrole-polycaprolactone-graphene ternary nanocomposite involves taking graphite powder, adding sodium nitrate and concentrated sulfuric acid, ice-water bath stirring, adding potassium permanganate, and reacting.
  • 专利号:   CN110729133-A
  • 发明人:   WEI L, DAI J, TANG P
  • 专利权人:   GUANGXI ACAD SCI APPLIED PHYSICS LAB
  • 国际专利分类:   C01B032/184, H01G011/24, H01G011/36, H01G011/48, H01G011/86
  • 专利详细信息:   CN110729133-A 24 Jan 2020 H01G-011/24 202014 Pages: 7 Chinese
  • 申请详细信息:   CN110729133-A CN11104639 13 Nov 2019
  • 优先权号:   CN11104639

▎ 摘  要

NOVELTY - A polypyrrole-polycaprolactone-graphene ternary nanocomposite is prepared by taking graphite powder, adding sodium nitrate and concentrated sulfuric acid, ice-water bath stirring, adding potassium permanganate, reacting, removing ice-water bath, heating, adding liquid volume to container, stirring and reacting, adding hydrogen peroxide solution, centrifuging, washing solid to neutral, re-dissolving in water, ultrasonicating, filtering, freeze drying to obtain graphene oxide, mixing dimethylacetamide and deionized water, adding graphene oxide, ultrasonicating, adding sodium bisulfite, stirring and reacting, filtering, washing with deionized water, freeze drying to obtain graphene, mixing with tetrahydrofuran, ultrasonicating, adding polycaprolactone and polypyrrole, stirring and dissolving, and electrospinning. USE - Method for preparing polypyrrole-polycaprolactone-graphene ternary nanocomposite. ADVANTAGE - The product has excellent electrochemical performance and has high specific surface area. DETAILED DESCRIPTION - A polypyrrole-polycaprolactone-graphene ternary nanocomposite is prepared by taking 2-3 g graphite powder, adding 1-1.5 g sodium nitrate and 46-69 mL concentrated sulfuric acid, ice-water bath stirring, adding 6-9 g potassium permanganate, reacting at 20 degrees C for 4-8 minutes, removing ice-water bath, heating at 32-37 degrees C for 25-40 minutes, adding 1.8-2.5 times liquid volume to container, stirring and reacting for 12-18 minutes, adding hydrogen peroxide solution, centrifuging, washing solid to neutral, re-dissolving in water, ultrasonicating for 10-20 minutes, filtering, freeze drying to obtain graphene oxide, mixing 600-750 mL dimethylacetamide and 400-500 mL deionized water, adding 1.0-1.2 g graphene oxide, ultrasonicating for 3-10 minutes, adding 5.6-6.8 g sodium bisulfite, stirring and reacting at 90-98 degrees C for 2.8-3.5 hours, filtering, washing 3-5 times with deionized water, freeze drying to obtain graphene, taking 2-10 g graphene, mixing with 20-30 mL tetrahydrofuran, ultrasonicating, adding 2-3 g polycaprolactone and 1-2 g polypyrrole, stirring and dissolving, and electrospinning.