• 专利标题:   Preparing black phosphorus-carbon composite material used in lithium/sodium ion battery field, comprises ball milling amorphous red phosphorus and conductive carbon material, compressing red phosphorus-carbon material mixed raw material, and performing high-temperature and high-pressure reaction.
  • 专利号:   CN115172711-A
  • 发明人:   HUANG H, CHING C, WU Y
  • 专利权人:   UNIV WUHAN TECHNOLOGY
  • 国际专利分类:   H01M004/36, H01M004/38, H01M004/587
  • 专利详细信息:   CN115172711-A 11 Oct 2022 H01M-004/36 202299 Chinese
  • 申请详细信息:   CN115172711-A CN10890698 27 Jul 2022
  • 优先权号:   CN10890698

▎ 摘  要

NOVELTY - Preparing black phosphorus-carbon composite material, comprises (a) ball milling the amorphous red phosphorus and the conductive carbon material under a protective atmosphere to obtain a red phosphorus-carbon material mixed raw material; (b) compressing the obtained red phosphorus-carbon material mixed raw material, and placing the obtained block sample into a high-temperature and high-pressure assembly; (c) placing the sample assembly into a high-temperature and high-pressure device to perform a high-temperature and high-pressure reaction, and taking out the sample after lowering the temperature and pressure to obtain the black phosphorus-carbon composite material. USE - The black phosphorus-carbon composite material is useful in field of lithium/sodium ion battery (claimed). ADVANTAGE - The method has high black phosphorus crystallinity, and relatively high covalent PC bond content, is beneficial to inhibit the volume expansion of black phosphorus during charging and discharging of lithium/sodium ion battery, maintains stable charge-discharge cycle performance, is simple and economical, and has controllable synthesis reaction, which is suitable for popularization and application. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is also included for black phosphorus-carbon composite material, prepared as mentioned above.