• 专利标题:   Selenium-coated nanocomposite material useful for preparing sodium ion battery electrode material, contains selenium, tin dioxide comprising tetragonal tin dioxide and orthorhombic tin dioxide and graphene.
  • 专利号:   CN107706404-A
  • 发明人:   WU X, WANG Y, HOU B, LV H
  • 专利权人:   UNIV NORTHEAST NORMAL
  • 国际专利分类:   H01M004/13, H01M004/36
  • 专利详细信息:   CN107706404-A 16 Feb 2018 H01M-004/36 201817 Pages: 9 Chinese
  • 申请详细信息:   CN107706404-A CN11178146 23 Nov 2017
  • 优先权号:   CN11178146

▎ 摘  要

NOVELTY - A selenium-coated nanocomposite material contains selenium, tin dioxide comprising tetragonal tin dioxide and orthorhombic tin dioxide and graphene. The selenium-coated nanocomposite material is prepared by growing tin dioxide on two different crystal phases to form nanoscale particles, uniformly bonding nanoscale particles to the three-dimensional conductive graphene surface, and uniformly coating disordered selenium on the tin dioxide/graphene nanostructured surface. USE - The selenium-coated nanocomposite material is useful for preparing sodium ion battery electrode material (claimed). ADVANTAGE - The selenium-coated nanocomposite material has excellent storage performance and synergistic effect. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is included for preparation method of selenium-coated nanocomposite material, which involves adding 2.48 g L-tartaric acid to 50 ml deionized water, adding 295 mu l anhydrous stannic chloride to the solution, adding 150 mg graphene oxide aqueous solution and stirring, continuously stirring, dripping 50 ml 0.1-0.8 mg/ml-1 sodium borohydride solution in the suspension and ultrasonically processing for 3-7 hours, centrifuging, washing the suspension with deionized water and absolute ethanol and vacuum drying at 80 degrees C to obtain tin intermediate product, uniformly mixing selenium powder with tin intermediate product, and calcining at 300-700 degrees C for 3-8 hours.