• 专利标题:   Preparation of fluorine polyhedral oligomeric silsesquioxane-modified propyl heptyl graphene oxide involves dropping one silane coupling agent in dodecafluoroheptyl propyl polyhedral oligomeric silsesquioxane, and ultrasonically dispersing.
  • 专利号:   CN104477904-A, CN104477904-B
  • 发明人:   GAO C, HE H, JIANG Y, CHENG Q, WANG M
  • 专利权人:   UNIV HOHAI
  • 国际专利分类:   C01B031/04
  • 专利详细信息:   CN104477904-A 01 Apr 2015 C01B-031/04 201540 Pages: 13 Chinese
  • 申请详细信息:   CN104477904-A CN10853801 31 Dec 2014
  • 优先权号:   CN10853801

▎ 摘  要

NOVELTY - A fluorine polyhedral oligomeric silsesquioxane-modified propyl heptyl graphene oxide is prepared by dropping silane coupling agent A in dodecafluoroheptyl propyl polyhedral oligomeric silsesquioxane, adding weak base catalyst A, stirring, reacting, adding graphene oxide, ultrasonically dispersing, reacting with dodecafluoroheptyl-terminated propyl polyhedral oligomeric silsesquioxane, adding weak base catalyst B, stirring, reacting, adding silane coupling agent B, stirring, and reacting. USE - Method for preparing fluorine polyhedral oligomeric silsesquioxane-modified propyl heptyl graphene oxide (claimed). ADVANTAGE - The method is simple. The product has high purity and low cost. DETAILED DESCRIPTION - A fluorine polyhedral oligomeric silsesquioxane-modified propyl heptyl graphene oxide is prepared by dropping silane coupling agent A in dodecafluoroheptyl propyl polyhedral oligomeric silsesquioxane at molar ratio of 1.01-3:1, adding weak base catalyst A, stirring, reacting at 20-80 degrees C for 1-8 hours, adding 0.1-5.0 wt.% graphene oxide, ultrasonically dispersing, reacting with dodecafluoroheptyl-terminated propyl polyhedral oligomeric silsesquioxane, adding weak base catalyst B, stirring, reacting at 20-80 degrees C for 1-9 hours, adding silane coupling agent B, stirring, and reacting at 20-80 degrees C for 6-42 hours.