• 专利标题:   Adsorption desulfurization catalyst, comprises graphene oxide and mono-disperse transition metal oxide, graphene oxide including edge region and conjugated region, and transition metal oxide embedded between graphene oxide layers.
  • 专利号:   CN112354536-A
  • 发明人:   CHEN Y
  • 专利权人:   GUANGZHOU LVRAN ENVIRONMENTAL PROTECTION NEW MATERIAL TECHNO
  • 国际专利分类:   B01J023/34, B01J037/00, B01J037/03, B01J037/08, B01J037/32, B01J037/34, C10G025/00
  • 专利详细信息:   CN112354536-A 12 Feb 2021 B01J-023/34 202133 Pages: 7 Chinese
  • 申请详细信息:   CN112354536-A CN11297473 18 Nov 2020
  • 优先权号:   CN11297473

▎ 摘  要

NOVELTY - Adsorption desulfurization catalyst, comprises graphene oxide and mono-disperse transition metal oxide. The graphene oxide includes an edge region and a conjugated region. The edge region has a carboxy group. The conjugated region has a hydroxy group and an epoxy group. At least part of the carboxy of the edge region of the graphene oxide is converted into an amide group. At least part of the conjugated region hydroxy of the graphene oxide is converted into carbamate. The mono-disperse transition metal oxide is embedded between the graphene oxide layers. USE - Used as an adsorption desulfurization catalyst. ADVANTAGE - The catalyst has an effect of rapidly adsorbing various sulfur-containing impurities in gasoline, and can remove the adsorbed impurities. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is also included for a method for preparing adsorption desulfurization catalyst, comprising (1) mixing the graphene oxide and isocyanate according to mass ratio of 1:3-1:5, under the protection state of inert gas, performing ultrasonic microwave reaction, and then filtering, washing and drying to obtain the pre-treated graphene oxide; and (2) dispersing the pre-treated graphene oxide in the transition metal salt solution, adjusting pH to alkaline, stirring and reacting, allowing to stand for aging, filtering, washing and drying, and then baking at low temperature below 120 degrees C to obtain the product.