• 专利标题:   Chemical modification of graphene oxide inorganic filler used for preparing epoxy resin composite material includes soaking inorganic filler, treating with silane coupling agent, adding graphene oxide into buffer solution and drying.
  • 专利号:   CN103788413-A, CN103788413-B
  • 发明人:   JIN X, WANG C, CHEN J, GE H, ZHAO D
  • 专利权人:   UNIV JINAN
  • 国际专利分类:   C08K007/14, C08K007/28, C08K009/02, C08K009/06, C08L063/00, C09C001/28, C09C003/04, C09C003/06, C09C003/12
  • 专利详细信息:   CN103788413-A 14 May 2014 C08K-009/06 201446 Pages: 13 Chinese
  • 申请详细信息:   CN103788413-A CN10034778 24 Jan 2014
  • 优先权号:   CN10034778

▎ 摘  要

NOVELTY - Chemical modification of graphene oxide inorganic filler comprises soaking inorganic filler into concentrate sulfuric acid and hydrogen peroxide mixture at 90 degrees C, performing hydroxylated surface treatment, washing, drying, treating with silane coupling agent, adding graphene oxide powder or graphene oxide solution into 2-(N-morpholino)ethanesulfonic acid (MES) buffer solution, controlling pH at 5.8-6.0, adding 1-ethyl-3-(3-dimethylaminopropyl)carbodiimide (EDC) and N-hydroxysuccinimide (NHS), ultrasonic treating, reacting with inorganic filler, filtering, washing, and drying. USE - Method for chemical modifying graphene oxide inorganic filler used for preparing epoxy resin composite material (all claimed). ADVANTAGE - The method is simple and environment-friendly. The graphene oxide inorganic filler has strong covalent bond and high mechanical strength. DETAILED DESCRIPTION - Chemical modification of graphene oxide inorganic filler comprises soaking inorganic filler into concentrate sulfuric acid and hydrogen peroxide mixture at 90 degrees C for 30 minutes, performing hydroxylated surface treatment, washing with water, drying, treating with silane coupling agent to obtain modified inorganic filler solution, adding graphene oxide powder or graphene oxide solution into 2-(N-morpholino)ethanesulfonic acid (MES) buffer solution, controlling pH at 5.8-6.0, adding 1-ethyl-3-(3-dimethylaminopropyl)carbodiimide (EDC) and N-hydroxysuccinimide (NHS), ultrasonic treating for 1-3 hours, reacting with inorganic filler, filtering, washing, and drying.