• 专利标题:   Preparing carbon-coated nickel manganese binary cobalt-free anode material, by subjecting ion exchange matrix, graphene and solvent for solvothermal reaction; and performing ion exchange to nickel manganese binary cobalt-free anode material.
  • 专利号:   CN113666432-A, CN113666432-B
  • 发明人:   WANG T, JIANG W, LI Z, YANG H, LI J, CHEN T, CUI J, REN H
  • 专利权人:   SVOLT ENERGY TECHNOLOGY CO LTD, SVOLT ENERGY TECHNOLOGY CO LTD
  • 国际专利分类:   C01B032/05, C01B032/184, C01B032/19, C01B032/198, C01G053/00, H01M010/0525, H01M004/36, H01M004/505, H01M004/525, H01M004/62
  • 专利详细信息:   CN113666432-A 19 Nov 2021 C01G-053/00 202234 Chinese
  • 申请详细信息:   CN113666432-A CN10877955 30 Jul 2021
  • 优先权号:   CN10877955

▎ 摘  要

NOVELTY - Preparing carbon-coated nickel manganese binary cobalt-free anode material, comprising: subjecting the ion exchange matrix, graphene and solvent for solvothermal reaction; where the ion exchange matrix uses formula of MOn and/or M(OH)n to obtain solution containing hydroxide/graphene composite material; Ksp of the hydroxide is (1x10-40 10-40) to (1x10-11), where M is group IIA, group IIIA, group IVA, group IIIB, group IVB, group VIB, group VIIB or group VIII, n is 2-4; performing ion exchange to the nickel manganese binary cobalt-free anode material and the M element in the solution containing hydroxide/graphene composite material to obtain the carbon-coated nickel manganese binary cobalt-free anode material. USE - The method is useful for preparing carbon-coated nickel manganese binary cobalt-free anode material. ADVANTAGE - The method can form a compact and stable carbon coating layer on the surface of the nickel-manganese binary cobalt-free anode material. DETAILED DESCRIPTION - INDEPENDENT CLAIMS are also included for: (1) carbon-coated nickel manganese binary cobalt-free anode material, prepared by the preparation method of carbon-coated ternary anode material; and the chemical formula of the carbon-coated nickel cobalt manganese ternary anode material is LiNixMn1-xO2-C, where x is 0.60-0.90; and (2) a lithium ion battery, comprising a positive electrode, a negative electrode, a membrane set between the positive electrode and the negative electrode, and electrolyte, where the positive electrode comprises the carbon-coated nickel manganese binary cobalt-free positive electrode material.