• 专利标题:   Preparation of corrosion-resistant composite coating involves adding dianhydride monomer to prepared dispersion liquid containing graphene oxide to obtain polyamic acid slurry and coating slurry on metal substrate and heating substrate.
  • 专利号:   CN106349923-A, CN106349923-B
  • 发明人:   SUN J, GU Y, WANG Y, LU X, ZHAI H, LU G
  • 专利权人:   SHANGHAI INST CERAMICS CHINESE ACAD SCI
  • 国际专利分类:   C08G073/10, C08K003/04, C09D179/08, C09D007/12, C09D007/61
  • 专利详细信息:   CN106349923-A 25 Jan 2017 C09D-179/08 201726 Pages: 19 Chinese
  • 申请详细信息:   CN106349923-A CN10744275 26 Aug 2016
  • 优先权号:   CN10744275

▎ 摘  要

NOVELTY - Preparation of corrosion-resistant composite coating involves dispersing graphene oxide in high boiling organic solvent, adding non-ionic surfactant to solvent, reacting mixture to obtain dispersion liquid of graphene organic solvent, adding dianhydride monomer and fluorinated diamine monomer to dispersion liquid, carrying out in-situ polymerization reaction of mixture for 12-48 hours to obtain graphene-containing polyamic acid slurry, coating prepared slurry on metal substrate by spin coating process and carrying out thermal imidization of coated metal substrate. USE - Preparation of corrosion-resistant composite coating (claimed). ADVANTAGE - The method provides composite coating with excellent high-temperature performance and optical transparency. DETAILED DESCRIPTION - Preparation of corrosion-resistant composite coating involves (a) dispersing graphene oxide in high boiling organic solvent by solvent displacement method, adding non-ionic surfactant to solvent, reacting mixture at 160-200 degrees C for 12-48 hours to obtained dispersion liquid of graphene organic solvent, (b) adding dianhydride monomer and fluorinated diamine monomer to dispersion liquid of graphene organic solvent, carrying out in-situ polymerization reaction of mixture for 12-48 hours to obtain graphene-containing polyamic acid slurry, and (c) coating prepared slurry on metal substrate by spin coating process and carrying out thermal imidization of coated metal substrate at 160-480 degrees C for 5-60 minutes.