• 专利标题:   Composite material for manufacturing fifth-generation (5G) mobile phone antenna material, comprises sulfur-containing polymer prepared by anionic ring-opening copolymerization reaction of sulfur-containing carbon monomer, epoxy monomer and acid anhydride under action of catalyst.
  • 专利号:   CN113372555-A, CN113372555-B
  • 发明人:   ZHANG X, FENG Z, CAO X
  • 专利权人:   UNIV ZHEJIANG
  • 国际专利分类:   C08G075/14, C08L081/04, C08L083/04, C08L027/18, C08L027/16, C08K007/26, C08K003/04
  • 专利详细信息:   CN113372555-A 10 Sep 2021 C08G-075/14 202188 Pages: 15 Chinese
  • 申请详细信息:   CN113372555-A CN10708415 25 Jun 2021
  • 优先权号:   CN10708415

▎ 摘  要

NOVELTY - A composite material comprises sulfur-containing polymer prepared by anionic ring-opening copolymerization reaction of sulfur-containing carbon monomer, epoxy monomer and acid anhydride under action of catalyst, where the epoxy monomer is selected from one or more of trifluoropropylene oxide, 3-(2,2,3,3-tetrafluoropropoxy)-1,2-propylene oxide, hexafluoropropylene oxide, heptafluorobutyl ethylene oxide, octafluoropentyloxy-1,2-propylene oxide, nonafluoropentyl ethylene oxide, perfluoro-2-methyl-2,3-epoxypentane, tridecafluoroheptyl ethylene oxide, glycidyl ether hexafluorononyl ether, naphthyl glycidyl ether, anthryl glycidyl ether, azophenyl glycidyl ether and biphenyl glycidyl ether. USE - Composite material with low dielectric constant and low dielectric loss, used for manufacturing Fifth-generation (5G) mobile phone antenna materials (claimed). ADVANTAGE - The composite material has low dielectric constant and low dielectric loss under high frequency, and the polymer main chain has no water-absorbing group. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is included for method for preparing composite material with low dielectric constant and low dielectric loss, which involves (1) blending sulfur-containing carbon monomer, epoxy monomer, acid anhydride, catalyst and optionally added solvent, and carrying out anionic ring-opening polymerization to obtain sulfur-containing polymer after post-treatment, (2) blending sulfur-containing polymer prepared in step (1), optionally added polymer additive, and optionally added nanoporous material, and hot-pressing.