• 专利标题:   Preparation of high electrical conductivity and high thermal conductivity bacterial cellulose/graphene composite paper, involves dispersing bacterial cellulose in water, mixing with e.g. graphene dispersion, dispersant, thickener and plasticizer, coating, drying and hot-pressing.
  • 专利号:   CN113583270-A
  • 发明人:   LING H, WANG X
  • 专利权人:   UNIV SOUTH CHINA TECHNOLOGY
  • 国际专利分类:   C08J005/18, C08J007/12, C08K003/04, C08L001/02, C08L003/04, C08L033/26, C08L005/04, C08L005/06, C08L071/02, C08L077/04
  • 专利详细信息:   CN113583270-A 02 Nov 2021 C08J-005/18 202222 Chinese
  • 申请详细信息:   CN113583270-A CN10841253 23 Jul 2021
  • 优先权号:   CN10841253

▎ 摘  要

NOVELTY - The preparation of high electrical conductivity and high thermal conductivity bacterial cellulose/graphene composite paper, involves (1) dispersing bacterial cellulose in water to make slurry to obtain bacterial cellulose slurry, (2) mixing bacterial cellulose slurry with graphene dispersion, dispersant, thickener and plasticizer uniformly to obtain bacterial cellulose/graphene composite slurry, and dispersing graphene in water to obtain graphene dispersion, (3) coating and drying composite slurry to obtain composite paper, (4) soaking composite paper is soaked in mixed solution of water-soluble calcium salt calcium and dilute nitric acid for post-treatment, washing with water, and drying, (5) hot-pressing the dried composite paper to obtain bacterial cellulose/graphene composite paper with high electrical conductivity and high thermal conductivity. USE - Preparation of high electrical conductivity and high thermal conductivity bacterial cellulose/graphene composite paper (claimed). ADVANTAGE - The method enables preparing high electrical conductivity and high thermal conductivity bacterial cellulose/graphene composite paper by simple and economical process, enabling complete adhesion of graphene and controllable doping amount, the prepared composite paper has conductivity of 54644.81 S/meter, through-surface thermal conductivity of 2.846 W/mK, and planar thermal conductivity of 42.597 W/mK, and the composite paper ensures enhanced mechanical properties and is bendable and foldable. DETAILED DESCRIPTION - The preparation of high electrical conductivity and high thermal conductivity bacterial cellulose/graphene composite paper, involves (1) dispersing bacterial cellulose in water to make slurry to obtain bacterial cellulose slurry, (2) mixing bacterial cellulose slurry with graphene dispersion, dispersant, thickener and plasticizer uniformly to obtain bacterial cellulose/graphene composite slurry, and dispersing graphene in water to obtain graphene dispersion, (3) coating and drying composite slurry to obtain composite paper, (4) soaking composite paper is soaked in mixed solution of water-soluble calcium salt calcium and dilute nitric acid for post-treatment, washing with water, and drying, (5) hot-pressing the dried composite paper to obtain bacterial cellulose/graphene composite paper with high electrical conductivity and high thermal conductivity, where the concentration of bacterial cellulose slurry in step (1) is 0.4-1.5 wt.%, the content of bacterial cellulose in step (2) is 15-85 wt.% of the paper mass, the content of graphene is 10-81 wt.% of paper mass, the content of dispersant is 0.4-2 wt.% of the paper mass, the content of thickener is 1-7 wt.% of the paper mass and the content of plasticizer is 0.25-1.8 wt.% of the paper mass, and the paper includes bacterial cellulose, graphene, dispersant, thickener and plasticizer.