• 专利标题:   Preparing barrier type polyester packaging material useful in daily necessities, comprises e.g. melting, mixing and extruding polyester, polymer, compatibilizer, functional auxiliary agent and two-dimensional filler, cooling and stretching.
  • 专利号:   CN113185810-A, CN113185810-B
  • 发明人:   MA P, NIU D, PAN J, YANG W, XU P
  • 专利权人:   UNIV JIANGNAN
  • 国际专利分类:   B29C055/12, B29D007/01, C08J005/18, C08K003/04, C08K003/34, C08K003/38, C08K005/1515, C08L023/08, C08L033/10, C08L067/02, C08L067/04, C08L069/00
  • 专利详细信息:   CN113185810-A 30 Jul 2021 C08L-067/02 202168 Pages: 12 Chinese
  • 申请详细信息:   CN113185810-A CN10404194 15 Apr 2021
  • 优先权号:   CN10404194

▎ 摘  要

NOVELTY - Preparing barrier type polyester packaging material comprises (i) taking 40-99 pts. wt. polyester A, 1-60 pts. wt. polymer B, 0.01-10 pts. wt. compatibilizer, 0.01-10 pts. wt. functional auxiliary agent and 0-5 pts. wt. two-dimensional filler, melting, mixing and extruding to form film or sheet and cooling quickly to 1-220 degrees C to make the crystallinity less than 20%; (ii) carrying out biaxially stretched of the cooled film or sheet under the temperature 1-150 degrees C and heating at more than 5-150 degrees C or (a) taking 40-99 pts. wt. polyester A, 1-60 pts. wt. polymer B, 0.01-10 pts. wt. compatibilizer, 0.01-10 pts. wt. functional auxiliary agent and 0-5 pts. wt. two-dimensional filler, melting and mixing and forming tube blank through the tubular machine head die and cooling the tube blank quickly to 1-220 degrees C to make the crystallinity less than 20 %; and (b) using the tube film biaxially stretched process to blow the cooled tube blank under the temperature of 1-150 degrees C, drafting and shaping. USE - The barrier type polyester packaging material is useful in daily necessities, chemical, food, food additives and medical packaging fields (all claimed). ADVANTAGE - The method: can solve technical issues that cause differences in barrier resistance in two component compatibility, control a particular biaxially stretched process to form a large amount of two-dimensional sheet structure, increases the diffusion path in the film in the film, so that the gas permeation coefficient can reduce 1-2 orders of magnitude; produces renewable macroscopically monolay layer; and produces high barrier packaging material which is easy to recover. DETAILED DESCRIPTION - Preparing barrier type polyester packaging material comprises (i) taking 40-99 pts. wt. polyester A, 1-60 pts. wt. polymer B, 0.01-10 pts. wt. compatibilizer, 0.01-10 pts. wt. functional auxiliary agent and 0-5 pts. wt. two-dimensional filler, melting, mixing and extruding to form film or sheet and cooling quickly to 1-220 degrees C to make the crystallinity less than 20%; (ii) carrying out biaxially stretched of the cooled film or sheet under the temperature 1-150 degrees C and heating at more than 5-150 degrees C or (a) taking 40-99 pts. wt. polyester A, 1-60 pts. wt. polymer B, 0.01-10 pts. wt. compatibilizer, 0.01-10 pts. wt. functional auxiliary agent and 0-5 pts. wt. two-dimensional filler, melting and mixing and forming tube blank through the tubular machine head die and cooling the tube blank quickly to 1-220 degrees C to make the crystallinity less than 20 %; (b) using the tube film biaxially stretched process to blow the cooled tube blank under the temperature of 1-150 degrees C, drafting and shaping, the polyester A comprises at least one of polyethylene glycol terephthalate, polylactic acid, lactic acid based copolymer, polybutylene terephthalate, polycarbonate or adipic acid/polybutylene terephthalate copolymer and the polymer B comprises at least one of glycolic acid homopolymer, glycolic acid copolymer, polyvinyl alcohol, vinyl alcohol copolymer, polypropylene carbonate or poly-hydroxy fatty acid esters. An INDEPENDENT CLAIM is also included for barrier type polyester packaging material, prepared as specified above.