• 专利标题:   Rechargeable lithium-sulfur battery comprises cathode comprising nanocomposite comprising graphene sheets with particles comprising sulfur adsorbed to graphene sheets and having specific average diameter, and electrolyte.
  • 专利号:   US2012088154-A1, WO2012047329-A2, WO2012047329-A3, EP2625735-A2, IN201300603-P2, JP2013539193-W, CN103155243-A, KR2013119432-A, US8753772-B2, CN103155243-B, EP2625735-A4
  • 发明人:   LIU J, LEMMON J P, YANG Z, CAO Y, LI X, REMON J P, JWIN R U
  • 专利权人:   BATTELLE MEMORIAL INST, BATTELLE MEMORIAL INST, BATTELLE MEMORIAL INST, BATTELLE MEMORIAL INST
  • 国际专利分类:   B82Y030/00, B82Y040/00, H01M004/583, H01M004/60, H01M004/88, H01M000/00, H01M010/05, H01M004/04, H01M004/58, H01M010/052, H01M010/0566, H01M004/36, H01M004/38, H01M004/136, H01M004/1397, H01M004/62
  • 专利详细信息:   US2012088154-A1 12 Apr 2012 H01M-004/583 201226 Pages: 9 English
  • 申请详细信息:   US2012088154-A1 US023241 08 Feb 2011
  • 优先权号:   US390945P, US023241, KR711213

▎ 摘  要

NOVELTY - Rechargeable lithium-sulfur battery comprises: a cathode; and an electrolyte, where the cathode comprises a nanocomposite comprising graphene sheets (100) with particles comprising sulfur adsorbed to the graphene sheets and having an average diameter less than 50 nm. USE - Used as rechargeable lithium-sulfur battery. ADVANTAGE - The rechargeable lithium-sulfur battery: exhibits reversible capacity of greater than 950 m Ah g-1 after 100 cycles; exhibits discharge capacity of at least 74% of initial capacity after 50 cycles at 0.1 C; and exhibits improved mechanical strength, chemical and electrochemical stability. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is also included for preparing a graphene-sulfur nanocomposite for the cathode in the rechargeable lithium-sulfur battery, comprising thermally expanding graphite oxide to yield graphene sheets, mixing the graphene sheets with a first solution comprising sulfur and carbon disulfide, evaporating the carbon disulfide to yield a solid nanocomposite, and grinding the solid nanocomposite to yield the graphene sulfur nanocomposite having sulfur particles (101) with an average diameter less than 50 nm. DESCRIPTION OF DRAWING(S) - The figure illustrates a graphene-sulfur nanocomposite arranged in an ordered stack. Graphene sheets (100) Sulfur particles (101)