• 专利标题:   Preparing graphene oxide functionalized metal organic framework useful for measuring concentration of gallium ions, adding zirconium tetrachloride and 2-amino-1,4-phthalic acid, placing in hydrothermal reaction kettle, washing with N,N-dimethylformamide and absolute ethanol, and centrifuging.
  • 专利号:   CN115591524-A
  • 发明人:   SHI J, FANG H, XU S, ZHOU C, LI W
  • 专利权人:   UNIV HEFEI TECHNOLOGY
  • 国际专利分类:   B01J020/22, B01J020/30, C22B003/24, C22B058/00
  • 专利详细信息:   CN115591524-A 13 Jan 2023 B01J-020/22 202317 Chinese
  • 申请详细信息:   CN115591524-A CN11289530 20 Oct 2022
  • 优先权号:   CN11289530

▎ 摘  要

NOVELTY - Preparing graphene oxide functionalized metal organic framework (UiO-66-NH2) comprises (i) pouring the graphene oxide into the reaction kettle, and adding N,N dimethylformamide, shaking and mixing, mixed solution, (ii) adding zirconium tetrachloride and 2-amino-1,4-phthalic acid into the mixed solution, shaking and mixing, placing in a hydrothermal reaction kettle for hydrothermal synthesis, (iii) cooling the product to room temperature, washing with N,N-dimethylformamide and absolute ethanol many times respectively, placing in a centrifuge for centrifugation to obtain an off-white powder, and (iv) rinsing off-white powder with absolute ethanol again, and drying once and adding in a vacuum oven for secondary drying. USE - The graphene oxide functionalized UiO-66-NH2 is useful for measuring concentration of gallium ions (claimed). ADVANTAGE - The adsorption rate of graphene oxide functionalized UiO66NH2 to gallium ions can reach more than 95%, and after repeated use, the adsorption rate of graphene oxide functionalized UiO66NH2 to gallium ions can still be maintained at more than 80%, and the cycle performance is high. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is also included for used method of graphene oxide functionalized UiO-66-NH2, comprising mixing graphene oxide functionalized UiO-66-NH2 with the gallium solution and shaken, after the adsorption is balanced, measuring concentration of gallium ions in the solution after adsorption, and eluting with an eluent.. DESCRIPTION OF DRAWING(S) - The drawing shows a process flow chart of graphene oxide functionalized UiO66NH2.