• 专利标题:   Supported palladium catalyst used for oxidation of formic acid, comprises specified amount of nanocrystalline palladium or palladium nanoalloy loaded on graphene nanocarrier.
  • 专利号:   CN104307512-A
  • 发明人:   CHENG G, DU C, LUO W
  • 专利权人:   UNIV WUHAN SUZHOU RES INST
  • 国际专利分类:   B01J023/44, B01J023/89
  • 专利详细信息:   CN104307512-A 28 Jan 2015 B01J-023/44 201527 Pages: 15 Chinese
  • 申请详细信息:   CN104307512-A CN10542678 14 Oct 2014
  • 优先权号:   CN10542678

▎ 摘  要

NOVELTY - A supported palladium catalyst contains 10-50 %mass nanocrystalline palladium or palladium nanoalloy loaded on graphene nanocarrier. USE - Supported palladium catalyst is used for oxidation of formic acid (claimed). ADVANTAGE - The supported palladium catalyst having adjustable morphology and size, and excellent dispersibility and activity is efficiently prepared at low reaction temperature, by simple method. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is included for preparation of supported palladium catalyst, which involves dissolving palladium salt in oleylamine, to form palladium salt solution having concentration of 5-10 mmol/L or dissolving cobalt salt or nickel salt and palladium salt in oleylamine to form mixed solution with palladium content of 5-10 mmol/L, adding boron-nitrogen compound to palladium salt solution or mixed solution, reacting at 90 degrees C or less for 30-60 minutes, adding an organic precipitating agent, centrifuging mixture, washing and drying mixture to obtain nanocrystalline palladium or palladium nanoalloy, dispersing palladium or palladium nanocrystalline nanoalloy in n-hexane, adding graphene at room temperature, centrifuging mixture, and drying mixture.