• 专利标题:   Synthesizing graphene in-situ nucleation lithium iron phosphate comprises e.g. taking iron(ii) hydroxide and reduction agent, preparing modified graphene oxide suspension, and adding iron(ii) hydroxide and reduction agent to the suspension.
  • 专利号:   CN105826524-A
  • 发明人:   CHEN Y, GU Y, LIU H, KONG W
  • 专利权人:   UNIV SHANDONG SCI TECHNOLOGY
  • 国际专利分类:   H01M010/0525, H01M004/36, H01M004/58, H01M004/62
  • 专利详细信息:   CN105826524-A 03 Aug 2016 H01M-004/36 201665 Pages: 12 Chinese
  • 申请详细信息:   CN105826524-A CN10158096 18 Mar 2016
  • 优先权号:   CN10158096

▎ 摘  要

NOVELTY - Synthesizing graphene in-situ nucleation lithium iron phosphate comprises (i) taking iron(ii) hydroxide and reduction agent, (ii) taking phosphoric acid, lithium hydroxide and graphene oxide, adding deoxygenated water, ultrasonically oscillating, evenly dispersing to form modified graphene oxide suspension, (iii) adding iron(ii) hydroxide and reduction agent to the modified graphene oxide suspension, and stirring evenly to obtain mixed solution, and (iv) adding the resulting mixed solution in a reaction kettle, stirring, introducing inert gas, heating, cooling, filtering, and drying. USE - The method is useful for synthesizing graphene in-situ nucleation lithium iron phosphate (claimed). ADVANTAGE - The lithium iron phosphate has excellent discharge performance at 20-50 degrees C. DETAILED DESCRIPTION - Synthesizing graphene in-situ nucleation lithium iron phosphate comprises (i) taking iron(ii) hydroxide and reduction agent, (ii) taking phosphoric acid, lithium hydroxide and graphene oxide, adding deoxygenated water, ultrasonically oscillating, evenly dispersing to form modified graphene oxide suspension, where mol ratio of iron, phosphorus and lithium is 1:1:1:4, and the addition amount of the graphene oxide is 0.5-5% of the iron(ii) hydroxide, (iii) adding iron(ii) hydroxide and reduction agent to the modified graphene oxide suspension, and stirring evenly to obtain mixed solution, and (iv) adding the resulting mixed solution in a reaction kettle, stirring along the edges, introducing inert gas, heating and preserving heat, cooling to room temperature, filtering, and drying.