• 专利标题:   Method for covering substrate with graphene transparent thin film for, e.g. solar cell, involves placing substrate in mixture of hydroxylamine (hydrochloride)/graphene oxide solution, depositing graphene oxide, and evaporating solvent.
  • 专利号:   CN103232033-A, CN103232033-B
  • 发明人:   CHANG Y, HAN G
  • 专利权人:   UNIV SHANXI
  • 国际专利分类:   C01B031/04
  • 专利详细信息:   CN103232033-A 07 Aug 2013 C01B-031/04 201403 Pages: 9 Chinese
  • 申请详细信息:   CN103232033-A CN10184384 17 May 2013
  • 优先权号:   CN10184384

▎ 摘  要

NOVELTY - A graphene oxide aqueous solution is prepared by Hummers method. A substrate is cleaned and dried. A hydroxylamine (hydrochloride) ethanol solution is filled in a container and the graphene oxide aqueous solution is injected. The substrate is placed in the container, graphene oxide is deposited at 0.5-6 mu g/cm2, the substrate is left still for 1 hour, solidified, and heated at low temperature, and the solvent is evaporated to form an N-doped graphene transparent film on the substrate surface. USE - Method for covering surface of substrate e.g. glass, plastic or quartz, with graphene transparent thin film (all claimed) useful as replacement of indium-tin oxide in organic solar cells, touch screens, and dye-sensitized solar cells. ADVANTAGE - The method enables simple formation of large quantities of transparent films having large area, high light transmittance, and high electrical conductivity. DETAILED DESCRIPTION - A graphene oxide aqueous solution with a concentration of 0.01-1 mg/mL is prepared by Hummers method. A substrate is cleaned using 0.5-1.5M hydrochloric acid for 10-50 minutes, washed with water, soaked in 70% alcohol for 5-30 minutes, washed with distilled water, and naturally dried. A hydroxylamine (hydrochloride) ethanol solution with a concentration of 0.02-2 mg/ml is filled in a container and the graphene oxide aqueous solution is injected. The substrate is placed in the container, graphene oxide is deposited at 0.5-6 mu g/cm2, the substrate is left still for 1 hour, solidified, and heated at low temperature, and the solvent is evaporated to form an N-doped graphene transparent film on the substrate surface.