• 专利标题:   Preparing functionalized graphene oxide-filled anticorrosive epoxy-phenolic hydroxy resin powder coating comprises e.g. mixing and reacting mixture of ethanol/water, titanium dioxide, silane coupling agent hydrolyzate and acetic acid.
  • 专利号:   CN108841292-A
  • 发明人:   WANG G
  • 专利权人:   WANG G
  • 国际专利分类:   C09D163/00, C09D005/08, C09D005/03, C09D007/61, C09D007/62, C08G059/62
  • 专利详细信息:   CN108841292-A 20 Nov 2018 C09D-163/00 201907 Pages: 5 Chinese
  • 申请详细信息:   CN108841292-A CN10616547 15 Jun 2018
  • 优先权号:   CN10616547

▎ 摘  要

NOVELTY - Preparing functionalized graphene oxide-filled anticorrosive epoxy-phenolic hydroxy resin powder coating comprises adding mixture of ethanol/water to the titanium dioxide, shearing and dispersing, adding silane coupling agent hydrolyzate, stirring and reacting, distilling, washing, drying, grinding to obtain modified titanium dioxide, ultrasonically stripping graphene oxide, adding tetrahydrofuran, and performing high-speed dispersion, ultrasonically dispersing, adding silane coupling agent and acetic acid, reacting in water bath, adding gallic acid based epoxy resin, uniformly stirring, cooling at room temperature and drying to obtain powdered functionalized graphene oxide, pre-mixing epoxy resin, phenolic hydroxy resin, alkaline accelerator, precipitated barium sulfate, modified titanium dioxide, powdered functionalized graphene oxide and other additives, transferring to a torque rheometer for melt blending, discharging, cooling, crushing, and sieving powder coating. USE - The method is useful for preparing functionalized graphene oxide-filled anticorrosive epoxy-phenolic hydroxy resin powder coating. DETAILED DESCRIPTION - Preparing functionalized graphene oxide-filled anticorrosive epoxy-phenolic hydroxy resin powder coating comprises adding mixture of ethanol/water to the titanium dioxide, shearing and dispersing under mechanical agitation, adding silane coupling agent hydrolyzate, stirring and reacting, vacuum-distilling, washing with ethanol, placing in oven and drying, grinding to obtain modified titanium dioxide, ultrasonically stripping graphene oxide, adding tetrahydrofuran, and performing high-speed dispersion, ultrasonically dispersing, adding silane coupling agent and acetic acid, reacting in water bath, adding gallic acid based epoxy resin, uniformly stirring, cooling at room temperature and drying to obtain powdered functionalized graphene oxide, pre-mixing epoxy resin, phenolic hydroxy resin, alkaline accelerator, precipitated barium sulfate, modified titanium dioxide, powdered functionalized graphene oxide and other additives, transferring to a torque rheometer for melt blending, discharging, cooling at room temperature, crushing with crusher, and sieving powder coating.