• 专利标题:   Synthesis of aqueous epoxy high-dispersion system for e.g. preparing ultra-high-strength concrete, involves epoxy reacting hydrophilic polyether segment and macromolecular resin and reacting epoxy curing agent and graphene.
  • 专利号:   CN107353397-A, CN107353397-B
  • 发明人:   ZHU D, SHEN Z, YANG Y, LI Q, LI W, CHEN T, SUN T
  • 专利权人:   JIANGSU COLOURFUL NEW BUILDING MATERIAL, JIANGSU FENGCAI ENERGY SAVING TECHNOLOGY
  • 国际专利分类:   C04B028/04, C08G059/22, C08G059/50, C08G065/333, C08G081/00, C09D163/00, C09D187/00, C09D005/10, C09D007/12, C09D005/24
  • 专利详细信息:   CN107353397-A 17 Nov 2017 C08G-059/50 201803 Pages: 13 Chinese
  • 申请详细信息:   CN107353397-A CN10623857 27 Jul 2017
  • 优先权号:   CN10623857

▎ 摘  要

NOVELTY - Glycidyl ether epoxy resin and double-ended amino small molecular amine are reacted at 60-65 degrees C for 3-4 hours, to obtain terminal-amino hydrophilic polyether segment. The terminal-amino hydrophilic polyether segment and macromolecular resin are epoxy reacted at 60-65 degrees C for 3-4 hours, to obtain nonionic self-emulsifying epoxy curing agent. The nonionic self-curing epoxy curing agent is reacted with low-oxidation-degree graphene and reacted at 60-65 degrees C for 3-4 hours, to obtain graphene-aqueous epoxy high dispersion system. USE - Synthesis of graphene-based aqueous epoxy high-dispersion system used for preparing ultra-high-strength concrete and aqueous epoxy anticorrosive paint (all claimed). ADVANTAGE - The method enables synthesis of graphene-based aqueous epoxy high-dispersion system with high conductivity and modulus, and excellent mechanical property. DETAILED DESCRIPTION - Glycidyl ether epoxy resin and double-ended amino small molecular amine in molar ratio of 1:(2-2.1) are reacted at 60-65 degrees C for 3-4 hours, to obtain terminal-amino hydrophilic polyether segment. The terminal-amino hydrophilic polyether segment and macromolecular resin in molar ratio of (2-2.1):1 are epoxy reacted at 60-65 degrees C for 3-4 hours, to obtain nonionic self-emulsifying epoxy curing agent. Low-oxidation degree graphene is prepared by ultrasound-assisted Hummers method. The nonionic self-curing epoxy curing agent is reacted with low-oxidation-degree graphene in molar ratio of (2-2.1):1 and reacted at 60-65 degrees C for 3-4 hours, to obtain graphene-aqueous epoxy high dispersion system. INDEPENDENT CLAIMS are included for the following: (1) super high-strength concrete and aqueous epoxy anticorrosive paint, which comprises graphene-aqueous epoxy high dispersion system; (2) preparation of ultra-high-strength concrete, which involves mixing 18-23 %mass sand, 32-35 %mass gravel, 42-45 %mass Portland cement and 2-3 %mass additive to form solid component, mixing 35-40 %mass graphene-aqueous epoxy high dispersion system and 60-65 %mass water to form liquid component, and mixing liquid component and solid component in mass ratio of 1:(5-7); and (3) preparation of aqueous epoxy anticorrosive paint, which involves mixing 90-95 %mass aqueous epoxy resin emulsion, 2-5 %mass deionized water and 1-5 %mass addition agent at room temperature for 5 minutes to obtain component (a), adding 85-90 %mass graphene-aqueous epoxy high dispersion system, adding and mixing 8-10 %mass deionized water and 1-5 %mass additive for two minutes and reacting mixture at normal temperature for 5 minutes to obtain component (b), mixing component (a), component (b) and zinc powder in mass ratio of 3:1:3 and stirring mixture.