• 专利标题:   Preparing ultra-high edge nitrogen-doped carbon nanosheets useful in potassium ion battery, comprises e.g. grafting reactive macromolecules to prepare graphene oxide-polymer molecular brushes, adding nitrogen-rich small molecules, hydrothermally reacting and freeze-drying, and carbonizing.
  • 专利号:   CN115784204-A
  • 发明人:   HUANG J, TANG Y, CEN Z, LIU S, WU D
  • 专利权人:   UNIV SUN YATSEN
  • 国际专利分类:   B82Y030/00, B82Y040/00, C01B032/15, H01M010/054, H01M004/583, H01M004/62
  • 专利详细信息:   CN115784204-A 14 Mar 2023 C01B-032/15 202328 Chinese
  • 申请详细信息:   CN115784204-A CN11529356 30 Nov 2022
  • 优先权号:   CN11529356

▎ 摘  要

NOVELTY - Preparing ultra-high edge nitrogen-doped carbon nanosheets comprises (i) grafting reactive macromolecules containing acid groups on the surface of graphene oxide to prepare graphene oxide-polymer molecular brushes; (ii) adding the nitrogen-rich small molecules containing amino groups to the aqueous solution of graphene oxide-polymer molecules, stirring, hydrothermally reacting and freeze-drying, and obtaining the self-assembled complex; and (iii) carbonizing the self-assembled composite in an inert gas to obtain ultra-high-edge nitrogen-doped carbon nanosheets. The reactive polymer is polyacrylic acid, polystyrene sulfonic acid, and/or polystyrene boric acid. The nitrogen-rich small molecules are melamine, urea, thiourea, cyanamide, and/or dicyandiamide. USE - The nanosheets are useful in potassium ion battery (claimed). ADVANTAGE - The nanosheets significantly improves the utilization of active sites and ion transport capabilities, and exhibits excellent rate performance and cycle stability when used as anodes for potassium-ion batteries. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is also included for ultra-high edge nitrogen-doped carbon nanosheets prepared by the above method.