• 专利标题:   Preparation of bionic electromagnetic shielding film involves adding mixed composition of magnetic particles-modified graphene composite material and polyvinyl alcohol to carbon fiber overlapped net-like film, heating, and pressing.
  • 专利号:   CN105038055-A, CN105038055-B
  • 发明人:   LI J, QU Z, WANG X, SUN H, WANG P, WANG Q, BAI L
  • 专利权人:   ORDNANCE ENG COLLEGE
  • 国际专利分类:   C08K003/04, C08K007/06, C08K009/00, C08L029/04
  • 专利详细信息:   CN105038055-A 11 Nov 2015 C08L-029/04 201632 Pages: 18 Chinese
  • 申请详细信息:   CN105038055-A CN10474042 06 Aug 2015
  • 优先权号:   CN10474042

▎ 摘  要

NOVELTY - Preparation of graded carbon fiber-graphene-based shell layered bionic electromagnetic shielding film involves preparing magnetic particles-modified graphene composite material (E), adding polyacrylamide and polyvinyl alcohol (P1) to deionized water, heating, adding short carbon fiber, forming rod-shaped carbon fiber overlapped net-like film, adding composite material (E) and polyvinyl alcohol (P2) to deionized water, heating, adding obtained mixed composition to rod-shaped carbon fiber overlapped net-like film, heating, and pressing in a mold to thickness of 0.1-1 mm. USE - Preparation of graded carbon fiber-graphene-based shell layered bionic electromagnetic shielding film (claimed). DETAILED DESCRIPTION - Preparation of graded carbon fiber-graphene-based shell layered bionic electromagnetic shielding film involves adding graphene oxide to deionized water (a), stirring, obtaining uniform dispersion of graphene oxide aqueous solution (A), adding glucose and 25-28 %mass aqueous ammonia solution to the solution (A), stirring, obtaining mixed solution (B), adding sodium hydroxide and iron chloride tetrahydrate to a mixed solution of deionized water (b) and ethanol, stirring, obtaining mixed solution (C), adding mixed solution (C) to the mixed solution (B), ultrasonically mixing, adding obtained mixed solution (D) to a reactor, heating at 120-200 degrees C for 4-12 hours, washing obtained black viscous product with deionized water and ethanol to remove salt and other residue, obtaining magnetic particles-modified graphene composite material (E), adding polyacrylamide and polyvinyl alcohol (P1) to deionized water (c), heating, adding short carbon fiber having length of 5-20 mm, forming rod-shaped carbon fiber overlapped net-like film, adding composite material (E) and polyvinyl alcohol (P2) to deionized water (d), heating at 85-90 degrees C for 12-24 hours, adding obtained mixed composition to rod-shaped carbon fiber overlapped net-like film, heating to 40-60 degrees C until water is evaporated, and pressing in a mold to thickness of 0.1-1 mm.