• 专利标题:   Surface functionalized spherical nano-silicon dioxide-graphene oxide/polymer composite tanning agent preparation involves mixing aqueous solution of polyvinyl alcohol-silicon dioxide and graphene oxide aqueous solution.
  • 专利号:   CN107541572-A, CN107541572-B
  • 发明人:   PAN H, WANG X, DING T, ZHANG J, LIU R
  • 专利权人:   UNIV HENAN, UNIV HENAN
  • 国际专利分类:   C14C003/04, C14C003/06, C14C003/22
  • 专利详细信息:   CN107541572-A 05 Jan 2018 C14C-003/04 201815 Pages: 16 Chinese
  • 申请详细信息:   CN107541572-A CN10821984 13 Sep 2017
  • 优先权号:   CN10821984

▎ 摘  要

NOVELTY - Surface functionalized spherical nano-silicon dioxide-graphene oxide/polymer composite tanning agent preparation involves mixing aqueous solution of polyvinyl alcohol-silicon dioxide (PVA-SiO2) or aqueous solution of polyethylene glycol-silicon dioxide (PEG-SiO2) and graphene oxide aqueous solution at 40-60 degrees C under stirring for 6-8 hours, and then centrifuging and drying to obtain polyvinyl alcohol-silicon dioxide-graphene oxide (PVA-SiO2-GO) or polyethylene glycol-silicon dioxide-graphene oxide (PEG-SiO2-GO). USE - Method for preparing surface functionalized spherical nano-silicon dioxide-graphene oxide/polymer composite tanning agent (claimed). ADVANTAGE - The method prepares the surface functionalized spherical nano-SiO2-graphene oxide/polymer composite tanning agent in a simple and cost-effective manner with improved wet and heat stability, and anti-static and flame retardant properties, and meets the performance requirements of the finished leather. DETAILED DESCRIPTION - Surface functionalized spherical nano-silicon dioxide-graphene oxide/polymer composite tanning agent preparation involves mixing aqueous solution of polyvinyl alcohol-silicon dioxide (PVA-SiO2) or aqueous solution of polyethylene glycol-silicon dioxide (PEG-SiO2) and graphene oxide aqueous solution at 40-60 degrees C under stirring for 6-8 hours, and then centrifuging and drying to obtain polyvinyl alcohol-silicon dioxide-graphene oxide (PVA-SiO2-GO) or polyethylene glycol-silicon dioxide-graphene oxide (PEG-SiO2-GO). The obtained polyvinyl alcohol-silicon dioxide-graphene oxide or polyethylene glycol-silicon dioxide-graphene oxide is weighed and added to vinyl polymer matrix by in-situ polymerization or solution blending method to prepare surface functionalized spherical nano-silicon dioxide-graphene oxide/polymer-based nanocomposting tanning agent. DESCRIPTION OF DRAWING(S) - The drawing shows a schematic infrared spectra of the prepared surface functionalized spherical nano-silicon dioxide-graphene oxide/polymer composite tanning agent. (Drawing includes non-English language text).