• 专利标题:   Preparing graphene oxide-polyaniline-nickel sulfide composite material used for lithium ion battery cathode, involves ultrasonically dispersing oxidized graphene in aqueous solution of sodium dodecyl sulfate and aniline.
  • 专利号:   CN106207111-A, CN106207111-B
  • 发明人:   HAN S, LIU J, WEI H, LIU Y, LIN H, AI Y, LI F, CHEN H, YU N, YU W
  • 专利权人:   SHANGHAI INST TECHNOLOGY, SHANGHAI INST TECHNOLOGY
  • 国际专利分类:   H01M010/0525, H01M004/36, H01M004/58, H01M004/62
  • 专利详细信息:   CN106207111-A 07 Dec 2016 H01M-004/36 201721 Pages: 7 Chinese
  • 申请详细信息:   CN106207111-A CN10552386 14 Jul 2016
  • 优先权号:   CN10552386

▎ 摘  要

NOVELTY - Preparing graphene oxide and polyaniline-nickel sulfide (GO-PANI-Ni3S2) composite material involves ultrasonically dispersing oxidized graphene in aqueous solution of sodium dodecyl sulfate and aniline for 10-50 minutes to obtain stable and uniform mixed solution. The mixture is stirred in ice water bath and hydrochloric acid is added dropwise to ammonium persulfate and stirred for 10-20hours. The mixture is centrifuged for 3-5 times to obtain polyaniline functionalized graphene. USE - Method for preparing GO-PANI-Ni3S2 composite material used for lithium ion battery cathode (claimed). ADVANTAGE - The method enables to prepare GO-PANI-Ni3S2 composite material which has high charging or discharging capacity and improve performance of the lithium ion battery. DETAILED DESCRIPTION - Preparing graphene oxide and polyaniline-nickel sulfide (GO-PANI-Ni3S2) composite material involves ultrasonically dispersing oxidized graphene in aqueous solution of sodium dodecyl sulfate and aniline for 10-50 minutes to obtain stable and uniform mixed solution. The mixture is stirred in ice water bath and hydrochloric acid is added dropwise to ammonium persulfate and stirred for 10-20hours. The mixture is centrifuged for 3-5 times to obtain polyaniline functionalized graphene. Polyaniline functionalized graphene is dispersed ultrasonically in 1 mole per liter hydrochloric acid solution and water is added. The obtained mixed liquid is stirred at room temperature for 1 hour and kept in a hydrothermal kettle at 180 degrees C for 12 hours to obtain the graphene oxide polyaniline hydroxide i.e. GO-PANI-Ni(OH)2 solution. Graphene oxide polyaniline hydroxide is cooled, poured into conical flask and added with sodium sulfide nonahydrate solution. The solution is centrifuged, washed for 3-5 times and dried to obtain lithium ion battery cathode material polyaniline coated with nickel sulfide.