• 专利标题:   PTFE composite material with anti-static function contains nano-tin oxide antimony, PTFE, carbon fiber, nano-tourmaline powder, steel fiber, fluororubber powder, acrylic acid, graphene oxide, silicon dioxide and dimethylformamide.
  • 专利号:   CN105907000-A
  • 发明人:   HU G
  • 专利权人:   ANHUI RONGDA VALVE CO LTD
  • 国际专利分类:   C08J007/04, C08K013/06, C08K003/22, C08K003/38, C08K007/06, C08K009/02, C08K009/06, C08L027/12, C08L027/18
  • 专利详细信息:   CN105907000-A 31 Aug 2016 C08L-027/18 201703 Pages: 5 Chinese
  • 申请详细信息:   CN105907000-A CN10473109 23 Jun 2016
  • 优先权号:   CN10473109

▎ 摘  要

NOVELTY - A PTFE composite material comprises 3-6 pts. wt. nano-tin oxide antimony, 80-90 pts. wt. PTFE, 10-15 pts. wt. carbon fiber, 1-3 pts. wt. nano-tourmaline powder, 5-10 pts. wt. steel fiber, 5-10 pts. wt. fluororubber powder, 1-3 pts. wt. acrylic acid, 1-3 pts. wt. graphene oxide, 5-10 pts. wt. silicon dioxide, 15-20 pts. wt. silane coupling agent KH550 (RTM: ( gamma )-aminopropyltriethoxysilane), 30-40 pts. wt. ethanol, acetic acid, 5-10 pts. wt. polyisocyanate JQ-1, dimethylformamide, 4-dimethylaminopyridine, dicyclohexyl carbodiimide and water. USE - PTFE composite material with anti-static function (claimed). ADVANTAGE - The PTFE composite material has improved tensile strength and excellent friction properties. The surface sintering state of the polytetrafluoroethylene is improved at high temperature sintering condition, so that bonding strength is significantly improved. The PTFE composite material has excellent anti-static function. DETAILED DESCRIPTION - A PTFE composite material comprises 3-6 pts. wt. nano-tin oxide antimony, 80-90 pts. wt. PTFE, 10-15 pts. wt. carbon fiber, 1-3 pts. wt. nano-tourmaline powder, 5-10 pts. wt. steel fiber, 5-10 pts. wt. fluororubber powder, 1-3 pts. wt. acrylic acid, 1-3 pts. wt. graphene oxide, 5-10 pts. wt. silicon dioxide, 15-20 pts. wt. silane coupling agent KH550 (RTM: ( gamma )-aminopropyltriethoxysilane), 95% of 30-40 pts. wt. ethanol, acetic acid, 5-10 pts. wt. polyisocyanate JQ-1, 15-20 pts. wt. dimethylformamide, 10-15 pts. wt. 4-dimethylaminopyridine, 15-20 pts. wt. dicyclohexyl carbodiimide and 90-100 pts. wt. water. The carbon fiber has a median length of 75-150 mu m. The median length of the steel fiber is 50-150 mu m. The fluororubber powder has a particle size of 80-200 mesh. An INDEPENDENT CLAIM is included for preparation of PTFE composite material, which involves (i) adding carbon fiber to 95% of 20-25 pts. wt. ethanol solvent, ultrasonically dispersing uniformly, adding acetic acid to adjust the pH to 4-5, adding 8-12 pts. wt. silane coupling agent KH550, stirring for 8-15 hours, then washing with deionized water, and vacuum drying, (ii) oxidizing the graphene oxide in the remaining 95% of ethanol solvent by glow discharge plasma technology to obtain graphene peroxide, (iii) adding the obtained graphene peroxide to dimethylformamide, ultrasonically processing for 2-3 hours, stirring, then sequentially adding 4-dimethylaminopyridine, dicyclohexyl carbodiimide and the treated carbon fiber, reacting at room temperature for 18-36 hours, then washing with deionized water, and vacuum drying to graphene peroxide-grafted carbon fiber, (iv) adding the fluororubber powder to the polyisocyanate JQ-1, mechanically stirring evenly, adding the dried steel fiber, nano-tin oxide antimony and nano-tourmaline powder, stirring for 1-3 hours, washing and drying to obtain mixture, (v) adding graphene peroxide-grafted carbon fiber and obtained mixture, homogeneously mixing with 70-75 pts. wt. PTFE in a high-speed mixer, cold forming, sintering in air atmosphere at 360-390 degrees C to plate-like sample having diameter of 150-250 mm and thickness of 3-4 mm, (vi) immersing the plate-like sample in a dipping coating solution for 4-8 minutes, drying in an oven at 80-100 degrees C, sintering in a muffle furnace at 120-200 degrees C for 10-30 minutes and taking out. The dipping coating solution is prepared by grinding silicon dioxide with remaining PTFE and silane coupling agent KH550, dispersing in water, and evenly and ultrasonically dispersing.