• 专利标题:   Preparing one-step synthetic graphene-coated iron doped carbon core-shell material comprises taking precursor containing glucose andferric hydroxide colloid, separating black solid phase product, washing, calcining in oxygen-free atmosphere.
  • 专利号:   CN113181915-A
  • 发明人:   YU Y, LI L, LIU C, MA R, CHANG Z, ZHANG X
  • 专利权人:   SOUTH CHINA INST ENVIRONMENTAL SCI
  • 国际专利分类:   B01J023/745, B01J035/02, C02F001/72, C02F101/34, C02F101/36
  • 专利详细信息:   CN113181915-A 30 Jul 2021 B01J-023/745 202177 Pages: 15 Chinese
  • 申请详细信息:   CN113181915-A CN10273794 15 Mar 2021
  • 优先权号:   CN10273794

▎ 摘  要

NOVELTY - Preparing one-step synthetic graphene-coated iron doped carbon core-shell material comprises (a) taking precursor containing 6-35 wt.% glucose and 4-12 wt.% ferric hydroxide colloid, thus molar ratio of glucose to ferric hydroxide colloid is 10-2:1, hydrothermally reacting at 160-240 degrees C for 4-18 hours and carrying out self-assembly to obtain black solid phase product and (b) separating black solid phase product obtained in step (a), washing, drying and calcining in oxygen-free atmosphere to obtain graphene-coated iron doped carbon core-shell material. USE - The method is useful for preparing one-step synthetic graphene-coated iron doped carbon core-shell. ADVANTAGE - The method utilizes low cost glucose as sole carbon source and ferric chloride as sole iron source to precisely adjust dosage of iron, carbon, hydrothermal time and hydrothermal temperature; has simple and fast process; and is environmentally friendly. DETAILED DESCRIPTION - INDEPENDENT CLAIMS are also included for: (1) iron doped carbon core-shell material prepared by above mentioned method comprising graphene shell and an inner iron core, where the inner iron core is zero-valent iron, iron tetroxide and iron sesquioxide; (2) use of iron doped carbon core-shell material in removing phenolic organic pollutants; and (3) catalytic degradation material of phenolic organic pollutants comprising persulfate and iron doped carbon core-shell material.