• 专利标题:   Preparing graphene-based zeolitic imidazolate framework-67 hydrogel material useful in lithium-ion batteries, comprises e.g. dissolving and dispersing cobalt chloride and polyvinyl pyrrolidone in methanol, dissolving 2-methyl imidazole in methanol, aging and performing chemical reduction reaction.
  • 专利号:   CN113943426-A
  • 发明人:   HUANG Y, XUE Y, HUANG C, KONG Y, ZHANG L, ZHANG W, LUO Y, LIN H
  • 专利权人:   SHANGHAI INST TECHNOLOGY
  • 国际专利分类:   C08G083/00, C08J003/075, C08K003/04, C08L087/00, H01M010/0525, H01M004/60, H01M004/62
  • 专利详细信息:   CN113943426-A 18 Jan 2022 C08J-003/075 202238 Chinese
  • 申请详细信息:   CN113943426-A CN11147691 29 Sep 2021
  • 优先权号:   CN11147691

▎ 摘  要

NOVELTY - Preparing graphene-based zeolitic imidazolate framework-67 (ZIF-67) hydrogel material comprises (1) dissolving and dispersing cobalt chloride and polyvinyl pyrrolidone in methanol to obtain solution A, dissolving the 2-methyl imidazole in methanol to obtain transparent B solution, adding solution B into the solution A, fully and vigorously stirring, and aging, (2) centrifuging the aged reaction liquid, washing with methanol for many times to obtain precipitate, removing impurities, and drying, (3) adding the polyethylene pyrrolidone modified ZIF-67 into graphene solution, ultrasonically stirring, centrifuging, and collecting the solution, and (4) adding sodium ascorbate solution, performing chemical reduction reaction at a certain temperature for a period of time, washing the composite precursor, and drying to obtain target product. USE - The graphene-based zeolitic imidazolate framework-67 hydrogel material is useful in lithium-ion batteries (claimed). ADVANTAGE - The method is environmentally friendly, has simple preparation process, is easy to operate, and is convenient for industrial production. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is also included for graphene-based zeolitic imidazolate framework-67 hydrogel material