• 专利标题:   Reactive nitrogen-phosphorus modified graphene modified polyurethane flame retardant material comprises nitrogen-phosphorus modified graphene, isophorone diisocyanate, polyester polyol, catalyst, chain extender, and dimethylolpropionic acid.
  • 专利号:   CN111533876-A
  • 发明人:   LIN D
  • 专利权人:   LIN D
  • 国际专利分类:   C01B032/198, C08G018/32, C08G018/34, C08G018/42, C08G018/66, C08G018/75, C08K003/04, C08K009/04
  • 专利详细信息:   CN111533876-A 14 Aug 2020 C08G-018/66 202073 Pages: 10 Chinese
  • 申请详细信息:   CN111533876-A CN10395609 12 May 2020
  • 优先权号:   CN10395609

▎ 摘  要

NOVELTY - Reactive nitrogen-phosphorus modified graphene modified polyurethane flame retardant material comprises nitrogen-phosphorus modified graphene, isophorone diisocyanate, polyester polyol, catalyst, chain extender and dimethylolpropionic acid in a mass ratio of 0.5-4:100:120-180:0.02-0.08:5-20:3-12. USE - Used as reactive nitrogen-phosphorus modified graphene modified polyurethane flame retardant material. ADVANTAGE - The material: promotes char formation rate and carbonization process of the material surface during the combustion process; and imparts excellent flame retardant properties of polyurethane materials. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is also included for preparing the material, comprising (1) adding polyester polyol and nitrogen-phosphorus modified graphene to isophorone diisocyanate, under nitrogen atmosphere uniformly ultrasonically dispersing, adding catalyst dibutyltin dilaurate, heating to 70-90 degrees C, reacting for 2-6 hours, reducing the temperature to 40-60 degrees C, adding acetone solvent and chain extender 1,4-butanediol, reacting for 1-3 hours, adding dimethylolpropionic acid for 1-2 hours, adding triethylamine to adjust the pH of the solution to neutral, and pouring the solution into a film forming mold to be cured to form a film.