• 专利标题:   Copper foil for manufacture of graphene used for e.g. separator, has sum total of crystal grain boundary length below preset value after heating under preset conditions in atmosphere containing hydrogen and argon.
  • 专利号:   JP2013237576-A, JP5918010-B2
  • 发明人:   YAMAJI T
  • 专利权人:   JX NIPPON MINING METALS CORP, JX NIPPON MINING METALS CORP
  • 国际专利分类:   C01B031/02, C22C009/00, C22C009/02, C22F001/00, C22F001/02, C22F001/08
  • 专利详细信息:   JP2013237576-A 28 Nov 2013 C01B-031/02 201381 Pages: 14 Japanese
  • 申请详细信息:   JP2013237576-A JP110233 14 May 2012
  • 优先权号:   JP110233

▎ 摘  要

NOVELTY - A copper foil (10) has sum total of crystal grain boundary length per surface unit area of less than 0.00800 mu m/ mu m2 after heating at 1000 degrees C for 1 hour in atmosphere containing 20 vol.% or more hydrogen and remainder of argon. USE - Copper foil used for manufacturing graphene (claimed). Uses include but are not limited to separator for fuel cell, thin film of display element, mercury-free fluorescent lamp, composite material and carrier of drug delivery system. ADVANTAGE - The copper enables manufacture of graphene having large area, economically. DETAILED DESCRIPTION - INDEPENDENT CLAIMS are included for the following: (1) manufacture of the copper foil, which involves carrying out high glossy rolling of copper foil base material with workability of 80-99.9% and oil-film equivalent of 13000-24000 at the time of final cold rolling; and (2) manufacture of graphene, which involves arranging heated copper foil in a chamber, supplying hydrogen gas and carbon containing gas, forming graphene (20) on the surface of the copper plating layer of the copper foil, etching the copper foil, after laminating a transfer sheet (30) on the surface of graphene and transferring graphene on the transfer sheet. DESCRIPTION OF DRAWING(S) - The drawing shows the process flow of the manufacture of graphene. Copper foil (10) Graphene (20) Transfer sheet (30) Etching tank (110) Sink roll (120)