• 专利标题:   Producing e.g. multi-graphene dispersion, useful as electrode material in lithium ion battery, comprises dispersing graphite oxide in dispersion medium to form multi-graphene oxide dispersion, and thermally reducing the oxide in dispersion.
  • 专利号:   EP2256087-A1, JP2010275186-A, KR2010127729-A, US2010301279-A1, AU2010202051-A1, CN101935036-A, TW201111280-A, KR1299863-B1, CN101935036-B, IL205905-A, US9045346-B2, JP5767443-B2, US2015270548-A1, TW507357-B1, US9548494-B2
  • 发明人:   NESPER R, TOMMY K, NESEUPEO R, TOMI K, NIRSBOR R, NISPORRE R, KASPAR T
  • 专利权人:   BELENOS CLEAN POWER HOLDING AG, BELENOS CLEAN POWER HOLDING AG, BELENOS CLEAN POWER HOLDING AG, BELENOS CLEAN POWER HOLDING AG, BALENOS CLEAN ENERGY CO LTD, NESPER R, KASPAR T
  • 国际专利分类:   C01B031/04, B01J013/00, C01B031/02, H01B001/04, H01B001/24, H01B013/00, H01M004/1393, H01M004/587, H01M004/583, B05D005/12, C01B003/00, H01M004/02, H01L021/31, B82Y030/00, B82Y040/00, C01B031/00, H01B013/32, H01M010/052
  • 专利详细信息:   EP2256087-A1 01 Dec 2010 C01B-031/04 201082 Pages: 17 English
  • 申请详细信息:   EP2256087-A1 EP161106 26 May 2009
  • 优先权号:   EP161106

▎ 摘  要

NOVELTY - Producing colloidal graphene dispersions or multi-graphene dispersions comprises: (a) dispersing graphite oxide in a dispersion medium to form a colloidal graphene oxide dispersion or a multi-graphene oxide dispersion; and (b) thermally reducing the graphene oxide or multi-graphene oxide in dispersion. USE - The method is useful for producing colloidal graphene dispersion or multi-graphene dispersion, and graphene or multi-graphene layer or multi-graphene particles, where the: colloidal graphene dispersion is useful for providing nanoparticles with an electronically conducting coating having a C/O ratio of at least 13.5; and multi-graphene (including multi-graphene with low C/O ratio) is useful as electrode material in rechargeable lithium ion batteries (all claimed). ADVANTAGE - The method: provides colloidal graphene dispersion or multi-graphene dispersions having high stability with improved intercalating features, thus making them suitable in the production of electrodes in rechargeable lithium ion batteries; and allows the production graphene layers in high yields without the need of additives or reducing agents. DETAILED DESCRIPTION - INDEPENDENT CLAIMS are also included for: (1) producing a graphene or multi-graphene layer or multi-graphene particles comprising steps (a), (b) as above per se, and either depositing on a substrate or precipitating the dispersion of step (a) and then performing step (b), or depositing on a substrate or precipitating the dispersion of step (b); (2) the colloidal graphene dispersion obtained by the method; (3) a multi-graphene dispersion or isolated multi-graphene with an inter-planar distance in the multi-graphene of greater than 3.35 Angstrom , preferably greater than 3.6 Angstrom ; (4) generating electronically conducting nanoparticles comprising coating nanoparticles with the graphene dispersion or graphene oxide dispersion and then thermally reducing the coated particles in dispersion to get nanoparticles coated with graphene/multi-graphene of a C/O ratio of at least 13.5; and (5) preparing an electrode for rechargeable lithium ion batteries, comprising providing the multi-graphene and coating a conductor with the multi-graphene, optionally in the presence of a binder.