• 专利标题:   Anode active material useful in anode for ternary lithium ion battery, comprises secondary particles formed by lithium-nickel-cobalt-manganese oxide accumulation, and coating layer including e.g. lithium cobaltate, lithium aluminate and lithium manganate.
  • 专利号:   CN113451560-A, CN113451560-B
  • 发明人:   KANG F, LI B, ZHANG L
  • 专利权人:   TSINGHUA SHENZHEN INT GRADUATE SCHOOL
  • 国际专利分类:   H01M010/0525, H01M004/131, H01M004/36, H01M004/505, H01M004/525
  • 专利详细信息:   CN113451560-A 28 Sep 2021 H01M-004/36 202218 Chinese
  • 申请详细信息:   CN113451560-A CN10744537 01 Jul 2021
  • 优先权号:   CN10744537

▎ 摘  要

NOVELTY - Anode active material comprises secondary particles formed by primary particle accumulation, and coating layer covered on the surfaces of the primary particles and the secondary particles. The primary particles is lithium-nickel-cobalt-manganese oxide (I). The coating layer is lithium cobaltate, lithium aluminate, lithium manganate, fluorine-doped lithium cobaltate, fluorine-doped lithium aluminate and/or fluorine-doped lithium manganate. (I) is prepared by reacting lithium-nickel-cobalt-manganese hydroxide ternary precursor and lithium salt in mass ratio of 1:1-1.5. USE - The anode active material is useful in anode for ternary lithium ion battery (all claimed). ADVANTAGE - The anode active material: ensures ternary lithium ion battery has long service life and better safety performance. DETAILED DESCRIPTION - Anode active material comprises secondary particles formed by primary particle accumulation, and coating layer covered on the surfaces of the primary particles and the secondary particles. The primary particles is lithium-nickel-cobalt-manganese oxide of formula (LiNi1-x-yCoxMnyO2) (I). The coating layer is lithium cobaltate, lithium aluminate, lithium manganate, fluorine-doped lithium cobaltate, fluorine-doped lithium aluminate and/or fluorine-doped lithium manganate. (I) is prepared by reacting lithium-nickel-cobalt-manganese hydroxide (Ni1-x-yCoxMny(OH)2) ternary precursor and lithium salt in mass ratio of 1:1-1.5. x, y = 0-0.4; and 1-x-y = greater than or equal to 0.6. INDEPENDENT CLAIMS are also included for: (1) preparation of the anode active material; and (2) anode, comprising conductive agent, a binder, and the anode active material.