• 专利标题:   Synthesis of polyethylene wax-graphene modified polypropylene composite material involves dispersing e.g. acyl chloride graphene in dichloromethane, reacting, centrifugally separating, washing, mixing with e.g. aminophenylphosphoryl bis-triazole modified graphene and molding.
  • 专利号:   CN115353684-A
  • 发明人:   LI M, HUANG L, ZHU H, MA H
  • 专利权人:   YANGZHOU KEBO NEW MATERIAL CO LTD
  • 国际专利分类:   C07F009/6518, C08K003/04, C08K009/04, C08L023/12, C08L051/06
  • 专利详细信息:   CN115353684-A 18 Nov 2022 C08L-023/12 202312 Chinese
  • 申请详细信息:   CN115353684-A CN10955434 10 Aug 2022
  • 优先权号:   CN10955434

▎ 摘  要

NOVELTY - Synthesis of polyethylene wax-graphene modified polypropylene composite material involves (s1) dispersing acyl chloride graphene, phenyl phosphoryl bis-amino triazole and triethylamine into dichloromethane at 0-5℃, stirring and reacting, centrifugally separating, and washing to obtain aminophenylphosphoryl bis-triazole modified graphene, and (s2) placing polypropylene, 1-8% aminophenylphosphoryl bis-triazole modified graphene and 0.5-2% maleic anhydride grafted polyethylene wax in twin-roller plastic mixer, mixing at 170-185℃, for 20-40 minutes, injecting and molding. USE - Synthesis of polyethylene wax-graphene modified polypropylene composite material (claimed). ADVANTAGE - The process uses polyethylene wax as compatilizer to improve the dispersibility and compatibility of graphene in polypropylene and has excellent improvement effect on comprehensive properties such as thermal stability of a polypropylene material, and uses aminophenylphosphoryl bisaminotriazole modified graphene as a graphene-nitrogen-phosphorus synergistic flame retardant and is thermally cracked to form stable expanded carbon layer during combustion to cover the surface of a material substrate, and has flame retardant effects of heat insulation, oxygen isolation and smoke suppression.