• 专利标题:   Catalyst for e.g. hydrogen fuel cell, comprises transition metal nanoparticles and metal boride carrier supporting transition metal nanoparticles, where transition metal nanoparticles comprise transition metals of group VIII and/or group IB.
  • 专利号:   CN112403461-A
  • 发明人:   LI R, LIU Z, YAN X, WEI T, CHEN S, LIANG S
  • 专利权人:   UNIV ZHEJIANG SCITECH
  • 国际专利分类:   B01J023/42, B01J023/44, B01J023/46, B01J023/50, B01J023/52, B01J023/72, B01J023/745, B01J023/75, B01J023/755, B01J035/02, C01B003/22
  • 专利详细信息:   CN112403461-A 26 Feb 2021 B01J-023/42 202126 Pages: 26 Chinese
  • 申请详细信息:   CN112403461-A CN11205550 02 Nov 2020
  • 优先权号:   CN11205550

▎ 摘  要

NOVELTY - Catalyst comprises transition metal nanoparticles and metal boride carrier (I) supporting the transition metal nanoparticles, where the transition metal nanoparticles comprise transition metals of group VIII and/or group IB. USE - The catalyst is used for catalyzing formic acid to produce hydrogen, multiphase catalytic reaction, hydrogen fuel cell, cathodic corrosion protection, boride target, boride nozzle composite material, boride ceramic material, boride coating, boride surface coating film material, wear-resistant material, energy chemical industry, petrochemical industry, carbon hydrogen bond activation, pharmacy, and preparation of hydrogen-containing water. ADVANTAGE - The catalyst has excellent high-temperature sintering performance. DETAILED DESCRIPTION - Catalyst comprises transition metal nanoparticles and metal boride carrier of formula: MmBn (I) supporting the transition metal nanoparticles, where the transition metal nanoparticles comprise transition metals of group VIII and/or group IB. M = metal, preferably Ti, Zr, Cr, Hf and W;and m:n = 0-4. An INDEPENDENT CLAIM is included for a method for synthesizing the catalyst, comprising (i) preparing transition metal nanoparticles and metal boride carrier separately, and (ii) loading the transition metal nanoparticles on the surface or inside of the metal boride support to prepare a metal nanocatalyst, stabilizing the metal nano-catalyst by heat treatment, and removing ligands and pollutants on the surface of the transition metal nano-particles at the same time to obtain the product, (or) (a) preparing metal boride carrier, and (b) using transition metal precursors to support metal nanoparticles on the metal boride carrier material by reduction or other loading methods to prepare metal nanocatalysts, stabilizing metal nano-catalyst by heat treatment, and removing ligands and pollutants on the surface of the transition metal nano-particles at the same time to obtain the product.