• 专利标题:   Preparing load type single-atom noble metal catalyst comprises preparing transition metal oxide nanoclusters-graphene composite materials, preparing of monoatomic precious metal sol, and loading.
  • 专利号:   CN112774690-A
  • 发明人:   GUO W, GUAN C, LANG J, ZHAO G, HUANG Z
  • 专利权人:   BEIJING HYPERION TECHNOLOGY CO LTD
  • 国际专利分类:   B01J021/18, B01J023/656, B01J023/89, B01J037/02, B01J037/12, B01J037/16, C07D215/06
  • 专利详细信息:   CN112774690-A 11 May 2021 B01J-023/89 202145 Pages: 12 Chinese
  • 申请详细信息:   CN112774690-A CN11064858 04 Nov 2019
  • 优先权号:   CN11064858

▎ 摘  要

NOVELTY - Preparing load type single-atom noble metal catalyst comprises (1) preparing transition metal oxide nanoclusters-graphene composite materials; (2) preparing of monoatomic precious metal sol; and (3) loading the monoatomic noble metal sol obtained in step (2) on the transition metal oxide nanoclusters-graphene composite material to obtain load type monoatomic noble metal catalyst. USE - The catalyst is useful in selective hydrogenation reaction of quinoline compounds (claimed). ADVANTAGE - The method: is economical, and simple; and has mild conditions, good repeatability and easy mass production. The catalyst: has monoatomic noble metals uniformly dispersed on the transition metal oxide nanocluster graphene composite material; and has high activity, high selectivity and high stability. DETAILED DESCRIPTION - INDEPENDENT CLAIMS are also included for: (1) load type single-atom noble metal catalyst is prepared by above mentioned method; and (2) use of load type single-atom noble metal catalyst in selective hydrogenation reaction of quinoline compounds, comprising adding quinoline compound and monoatomic noble metal catalyst into the solvent, stirring at 25-120 degrees C, 0.5-2 MPa hydrogen for 1-12 hours, the molar ratio of the catalyst to the quinoline compound is (0.01-0.05):1.