• 专利标题:   Preparation of modified membrane for sulfur lithium battery, involves adding zeolitic imidazolate framework-67 and polyvinylidene fluoride, adding N-methyl pyrrolidone, coating slurry on membrane surface, and vacuum drying.
  • 专利号:   CN115810864-A
  • 发明人:   WANG Q, JIAO J, HUI R, GE M, LU Y, ZHANG F, WANG J, CUI D
  • 专利权人:   SHANGHAI NAT ENG RES CENT NANOTECHNOLOGY
  • 国际专利分类:   H01M010/052, H01M010/058, H01M010/42, H01M050/403, H01M050/449
  • 专利详细信息:   CN115810864-A 17 Mar 2023 H01M-050/403 202327 Chinese
  • 申请详细信息:   CN115810864-A CN11588828 12 Dec 2022
  • 优先权号:   CN11588828

▎ 摘  要

NOVELTY - Preparing a modified membrane comprises mixing zeolitic imidazolate framework-67 (ZIF-67) doped reduced graphene oxide (rGO) (ZIF-67@rGO) and binder polyvinylidene fluoride (PVDF) according to 9:(0-3) to obtain a coating slurry. The coating slurry is uniformly coated on the surface of the separator (Celgard2400 separator), and then dried in a vacuum to obtain the ZIF-67@rGO modified separator. USE - Method for preparing a modified membrane for lithium-sulfur batteries. ADVANTAGE - The modified membrane shows excellent cycle performance and multiplying power performance when it is used for a sulfur lithium battery. The method is simple, cost-effective, environment-friendly, and has good industrial application prospect. DETAILED DESCRIPTION - INDEPENDENT CLAIMS are also included for the following: (1) a MOF@rGO modified membrane for lithium-sulfur batteries, which is prepared according to the method; and (2) a method for using the MOF@rGO modified membrane, which involves using modified membrane for lithium-sulfur batteries.