• 专利标题:   Graphite alkenyl functional film composite material comprises pyrenyl and amphiphilic ruthenium complex molecule formed by assembling graphene on substrate.
  • 专利号:   CN104681282-A, CN104681282-B
  • 发明人:   LI K, WANG H, YANG L, WEI Y, ZHU X
  • 专利权人:   UNIV KUNMING SCI TECHNOLOGY
  • 国际专利分类:   C01B031/04, H01G009/042, H01G009/20, C01B032/20
  • 专利详细信息:   CN104681282-A 03 Jun 2015 H01G-009/042 201567 Pages: 20 Chinese
  • 申请详细信息:   CN104681282-A CN10841639 30 Dec 2014
  • 优先权号:   CN10841639

▎ 摘  要

NOVELTY - The graphite alkenyl functional film composite comprises a pyrenyl and amphiphilic ruthenium complex molecule formed by assembling graphene on substrate. The graphite is dipped in zirconium oxychloride solution, ruthenium complex solution and zirconium ion. The ruthenium complex molecule is connected with amphiphilic character ruthenium complex (I-II). USE - Graphite alkenyl functional film composite material. ADVANTAGE - The graphite alkenyl functional film composite has high film and substrate combining strength and good popularization and application value, and can be prepared in a simple and precise manner. DETAILED DESCRIPTION - The graphite alkenyl functional film composite comprises a pyrenyl and amphiphilic ruthenium complex molecule formed by assembling graphene on substrate. The graphite is dipped in zirconium oxychloride solution, ruthenium complex solution and zirconium ion. The ruthenium complex molecule is connected with amphiphilic character ruthenium complex of formulae (I-II). An INDEPENDENT CLAIM is included for a method for preparing graphite alkenyl functional film composite, which involves: (A) dissolving amphiphilic ruthenium complex in ultrapure water and hydrochloric acid to prepare amphiphilic ruthenium complex solution; (B) dissolving oxychloride in ultrapure water to prepare oxychloride solution; (C) dissolving sodium lauryl sulfate in water to give aqueous sodium lauryl sulfate solution; (D) dispersing graphene in the aqueous solution to form graphene solution; (E) centrifuging the formed solution to remove residue at bottom of ultrasonic dispersion treatment to give a graphene dispersion; (F) immersing indium tinoxide substrate in the formed dispersion; (G) drying the substrate at room temperature in inert gas to obtain a graphene substrate; (H) immersing the graphene substrate in amphiphilic ruthenium complex solution at room temperature for 6-12 hours; (I) immersing the obtained substrate in zirconyl chloride solution at room temperature for 1.5-3.5 hours; and (J) drying the impregnated substrate for 3-6 hours at room temperature in inert gas. DESCRIPTION OF DRAWING(S) - The drawing shows a graphical representation depicting contact angle with changes in the number of assembled layers. (Drawing includes non-English language text).