• 专利标题:   Preparing polyimide film with good thermal conductivity and thermal stability, comprises e.g. dispersing graphene oxide into N,N-dimethylacetamide, adding zinc salt, aminoimidazole and methylimidazole, heating and stirring for reaction, centrifuging, washing and freeze-drying.
  • 专利号:   CN115386111-A
  • 发明人:   JIN H, PANG C, XU B, SUN S
  • 专利权人:   ANHUI GUOFENG NEW MATERIAL TECHNOLOGY CO, ANHUI GUOFENG NEW MATERIALS CO LTD
  • 国际专利分类:   C08G073/10, C08J005/18, C08K003/04, C08L079/08, C08L087/00
  • 专利详细信息:   CN115386111-A 25 Nov 2022 C08J-005/18 202308 Chinese
  • 申请详细信息:   CN115386111-A CN10867701 21 Jul 2022
  • 优先权号:   CN10867701

▎ 摘  要

NOVELTY - Preparing polyimide film with good thermal conductivity and thermal stability, comprises (i) dispersing graphene oxide into N,N-dimethylacetamide, adding zinc salt, aminoimidazole and methylimidazole, heating and stirring for reaction, adding hydrazine hydrate to the reaction system, stirring reaction, cooling to room temperature, centrifuging, washing and freeze-drying to obtain the aminated ZIF-loaded graphene composite material ammonia- zeolitic imidazolate framework-reduced graphene oxide (NH2-ZIFs-RGO), (ii) adding diamine monomer and NH2-ZIFs-RGO into organic solvent respectively to obtain diamine solution and NH2-ZIFs-RGO dispersion, adding part of dibasic anhydride monomers to diamine solution, stirring and adding NH2-ZIFs-RGO dispersion liquid, stirring and adding remaining dibasic anhydride monomers to adjust viscosity to prepare ZIFs-polyamic acid of RGO, and (iii) coating polyamic acid containing ZIFs-RGO to form film, heating and imidizing in stages, and cooling. USE - Preparing polyimide film with good thermal conductivity and thermal stability. ADVANTAGE - The polyimide film has high thermal conductivity and thermal stability, good mechanical performance, and good popularization. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is included for polyimide film with good thermal conductivity and thermal stability prepared according to above mentioned method.