• 专利标题:   Preparation of 1,3-cyclohexanedione involves adding palladium graphene catalyst, and resorcinol dissolved in dichloromethane into reactor, introducing hydrogen gas, reacting, and post-treating reaction solution.
  • 专利号:   CN104860802-A, CN104860802-B
  • 发明人:   WEI Z
  • 专利权人:   UNIV ZHEJIANG
  • 国际专利分类:   B01J023/44, C07C045/51, C07C049/403
  • 专利详细信息:   CN104860802-A 26 Aug 2015 C07C-045/51 201623 Pages: 8 Chinese
  • 申请详细信息:   CN104860802-A CN10184896 17 Apr 2015
  • 优先权号:   CN10184896

▎ 摘  要

NOVELTY - Preparation of 1,3-cyclohexanedione involves adding palladium graphene catalyst, and resorcinol dissolved in dichloromethane into reactor, introducing hydrogen gas, reacting at 20-60 degrees C for 0.5-3 hours under hydrogen pressure of 0.1-2 MPa, and post-treating the reaction solution. USE - Preparation of 1,3-cyclohexanedione (claimed). ADVANTAGE - The method enables simple preparation of 1,3-cyclohexanedione with high selectivity without using large amount of organic and inorganic salts.