• 专利标题:   Preparation of graphene-modified waterborne epoxy resin involves dissolving epoxy resin and fatty acid in solvent, reacting with neutralizer, layering, adding crosslinking agent and catalyst, placing graphene oxide, and heating.
  • 专利号:   CN113502033-A
  • 发明人:   WANG C, LI Q
  • 专利权人:   SHENZHEN GUSEN TECHNOLOGY CO LTD
  • 国际专利分类:   C08G059/40, C08G059/14, C08K003/04, C08L063/02
  • 专利详细信息:   CN113502033-A 15 Oct 2021 C08L-063/02 202198 Chinese
  • 申请详细信息:   CN113502033-A CN10810577 16 Jul 2021
  • 优先权号:   CN10810577

▎ 摘  要

NOVELTY - Preparation of graphene-modified waterborne epoxy resin comprises dissolving epoxy resin and fatty acid in solvent, putting in a reaction device, adding first catalyst, filling reaction device with nitrogen, heating for 20-80degreesC, stirring, and reacting for 6-24 hours; adding neutralizer to the reaction device, heating at 10-70degreesC, and reacting for 1-8 hours; removing unreacted fatty acid, catalyst and solvent and standing for layering; adding crosslinking agent and second catalyst into the reaction device, heating at 100-170degreesC, and reacting for 9-36 hours; placing graphene oxide in deionized water, stirring, and removing undissolved graphene oxide by filtration; and putting the graphene oxide solution into a reaction device, heating at 50-100degreesC, reacting for 18-72 hours, and cooling to room temperature. USE - The method is used for preparing graphene-modified waterborne epoxy resin. ADVANTAGE - The method is simple and does not generate toxic gas. The epoxy resin still has good reaction performance after curing. DETAILED DESCRIPTION - Preparation of graphene-modified waterborne epoxy resin comprises dissolving 40-50 pts. wt. epoxy resin and 10-30 pts. wt. fatty acid in 5-15 pts. wt. solvent, putting in a reaction device, adding 0.1-1 pt. wt. first catalyst, filling reaction device with nitrogen, heating for 20-80degreesC, stirring, and reacting for 6-24 hours; adding 10-20 pts. wt. neutralizer to the reaction device, heating at 10-70degreesC, and reacting for 1-8 hours; removing unreacted fatty acid, catalyst and solvent and standing for layering; adding 0.1-10 pts. wt. crosslinking agent and 0.1-1 pt. wt. second catalyst into the reaction device, heating at 100-170degreesC, and reacting for 9-36 hours; placing 2-5 pts. wt. graphene oxide in 5-10 pts. wt. deionized water, stirring at 4000-8000 revolutions/minute, and removing undissolved graphene oxide by filtration; and putting the graphene oxide solution into a reaction device, heating at 50-100degreesC, reacting for 18-72 hours, and cooling to room temperature.