• 专利标题:   High-temperature-resistant proton-exchange membrane for, e.g. fuel cell, comprises sulfonated polytrifluorostyrene resin, perfluorosulfonic acid resin, and sulfonated graphene having preset size, thickness, and carbon/sulfur ratio.
  • 专利号:   CN104927225-A, CN104927225-B
  • 发明人:   HAO J, JIANG Y, LI J
  • 专利权人:   SUZHOU GAOTONG NEW MATERIAL TECHNOLOGY, SUZHOU GAOTONG NEW MATERIAL TECHNOLOGY
  • 国际专利分类:   C08J005/22, C08K003/04, C08K009/04, C08L101/04, C08L025/18, H01M008/10, H01M008/1048, H01M008/1069
  • 专利详细信息:   CN104927225-A 23 Sep 2015 C08L-025/18 201578 Pages: 5 Chinese
  • 申请详细信息:   CN104927225-A CN10226322 06 May 2015
  • 优先权号:   CN10226322

▎ 摘  要

NOVELTY - A high-temperature-resistant proton-exchange membrane comprises 20-70 wt.% sulfonated polytrifluorostyrene resin, 10-50 wt.% perfluorosulfonic acid resin, and 0.01-2 wt.% sulfonated graphene having a particle size of 500 nm to 50 mu m, a thickness of 1-20 nm, and a carbon/sulfur molar ratio of 12:1-6:1. USE - High-temperature-resistant proton-exchange membrane is used in fuel cells, liquid flow batteries, and chlor-alkali industries. ADVANTAGE - The high-temperature-resistant proton-exchange membrane has excellent proton conductivity and oxidation resistance, and a use life of more than 5000 hours. The membrane can be prepared by a simple, economical, safe and environmentally-friendly method. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is included for preparation of proton-exchange membrane, which involves dissolving the three components in a mass ratio of 0.01-2:20-70:10-50 in an organic solvent to obtain a mixed solution, casting the mixed solution, and drying at 60-150 degrees C.