▎ 摘 要
NOVELTY - Synthesizing 1,3-butadiynes by heterogeneous catalysis comprises N,N-dimethylformamide (DMF) solution, adding aryl-substituted alkynes, oxygen (O2) and the nitrogen-doped graphene-supported copper catalyst are fully stirring and reacting at a certain temperature. USE - The method is useful for synthesizing 1,3-butadiynes by heterogeneous catalysis. ADVANTAGE - The method is simple, convenient and environmentally-friendly, has low production cost, recycles multiple of catalyst, has mild reaction condition, has high yield of product and has high reaction characteristics.