• 专利标题:   Method for synthesizing single atom catalyst useful in fuel cell, involves comprises e.g. using dimethylimidazole, zinc nitrate, and graphene oxide as solute andnhydrous methanol as solvent, stirring, pyrolyzing sulfur/zeolitic imidazolate framework-8-graphene oxide, cooling and pyrolyzing precursor.
  • 专利号:   CN115377435-A
  • 发明人:   DAI G, FU Y, ZHU J, XU H, XIA J, QIAN X, LI N, CHEN H, LI L, HE G
  • 专利权人:   UNIV CHANGZHOU
  • 国际专利分类:   H01M004/88, H01M004/90
  • 专利详细信息:   CN115377435-A 22 Nov 2022 H01M-004/88 202202 Chinese
  • 申请详细信息:   CN115377435-A CN10896588 28 Jul 2022
  • 优先权号:   CN10896588

▎ 摘  要

NOVELTY - The method comprises (1) using dimethylimidazole, zinc nitrate, and graphene oxide as the solute and anhydrous methanol as the solvent, stirring to obtain zeolitic imidazolate framework-8-graphene oxide (ZIF-8-GO), (2) using zeolitic imidazolate framework-8-graphene oxide and thiourea as solutes and anhydrous methanol as solvent to form sulfur/zeolitic imidazolate framework-8-graphene oxide through stirring and adsorption, (3) pyrolyzing sulfur / zeolitic imidazolate framework-8-graphene oxide in the atmosphere of protective gas to form porous sulfur-doped carbon (S, N-C), (4) cooling sulfur-doped carbon, adding phenanthroline (Phen) and transition metal source (M) to sulfur-doped carbon to form precursor M/S, N-C-Phen, and (5) pyrolyzing the precursors of M/S and N-C-Phen in the atmosphere of protective gas to obtain single-atom catalysts. USE - Method for synthesizing single atom catalyst, which is used in electro-catalysis application of single-atom catalyst, which is useful in fuel cell. ADVANTAGE - The synthesis method is simple and efficient, can be used for large-scale synthesis of single-atom catalysts, and is suitable for the synthesis of various metal single-atom catalysts, and solves the shortcomings of complex synthesis and difficulty in large-scale preparation. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is also included for a single atom catalyst.