• 专利标题:   Preparation of graphene/ultra-long titanium dioxide (B) nano composite material for lithium ion battery, involves dispersing graphene oxide and long-chain titanate nanotubes precursor, filtering to obtain solid mixture, and calcining.
  • 专利号:   CN106207112-A, CN106207112-B
  • 发明人:   YUAN S, XIONG J, JIANG G, CHEN S, HU Z
  • 专利权人:   UNIV HUBEI TECHNOLOGY, UNIV HUBEI TECHNOLOGY
  • 国际专利分类:   B82Y030/00, B82Y040/00, H01M010/0525, H01M004/36, H01M004/48, H01M004/62
  • 专利详细信息:   CN106207112-A 07 Dec 2016 H01M-004/36 201711 Pages: 10 Chinese
  • 申请详细信息:   CN106207112-A CN10559790 15 Jul 2016
  • 优先权号:   CN10559790

▎ 摘  要

NOVELTY - The preparation method of graphene/ultra-long titanium dioxide (B) nano composite material involves reacting titanium dioxide in alkaline solution, stirring, cooling, separating and washing to obtain long-chain titanate nanotubes, soaking in acidic solution, suction-filtering, and washing to obtain long-chain titanate nanotubes precursor, preparing graphene oxide, and uniformly dispersing the graphene oxide and the long-chain titanate nanotubes precursor, filtering to obtain solid mixture, and calcining the obtained solid mixture. USE - Preparation method of graphene/ultra-long titanium dioxide (B) nano composite material for lithium ion battery. ADVANTAGE - The method enables preparation of graphene/ultra-long titanium dioxide (B) nano composite material with excellent conductive performance, and improved electrochemical performance. DETAILED DESCRIPTION - The preparation method of graphene/ultra-long titanium dioxide (B) nano composite material involves (1) reacting titanium dioxide in alkaline solution, controlling the stirring speed at 300-900 rpm during the reaction, cooling the mixture to room temperature, separating and washing to obtain long-chain titanate nanotubes, soaking the long-chain titanate nanotubes in acidic solution, suction-filtering, and washing to neutral to obtain long-chain titanate nanotubes precursor by multiple ion exchange, (2) preparing graphene oxide by Hummers method, and (3) uniformly dispersing the graphene oxide obtained in the step (2) and the long-chain titanate nanotubes precursor obtained in step (1), filtering to obtain solid mixture, and calcining the obtained solid mixture under the protection of inert atmosphere.