• 专利标题:   Perovskite solar cell comprises transparent substrate, electron-transport layer, conductive cathode perovskite active layer, bulk heterojunction-doped hole-transport layer containing tetrakis-spirobifluorene, and metal anode.
  • 专利号:   CN113193119-A, CN113193119-B
  • 发明人:   YU J, LI J, WANG R, WANG Z
  • 专利权人:   UNIV CHINA ELECTRONIC SCI TECHNOLOGY
  • 国际专利分类:   H01L051/42, H01L051/46, H01L051/48
  • 专利详细信息:   CN113193119-A 30 Jul 2021 H01L-051/42 202173 Pages: 10 Chinese
  • 申请详细信息:   CN113193119-A CN10587818 27 May 2021
  • 优先权号:   CN10587818

▎ 摘  要

NOVELTY - A perovskite solar cell comprises from top to bottom, a transparent substrate, a conductive cathode, an electron-transport layer, a perovskite active layer, a bulk heterojunction comprising 2,2'-((4,4,9,9-tetrakis(4-hexylphenyl)-4,9-dihydro-s-indaceno(1,2-b:5,6-b')dithiophene-2,7-diyl)bis((4-((2-ethylhexyl)oxy)-5,2-thiophenediyl)methylidyne(5,6-difluoro-3-oxo-1H-indene-2,1(3H)-diylidene)))bis(propanedinitrile) (IEICO-4F), or poly(4,8-bis(5-(2-ethylhexyl)thiophen-2-yl)benzo(1,2-b;4,5-b')dithiophene-2,6-diyl-alt-(4-(2-ethylhexyl)-3-fluorothieno(3,4-b)thiophene-)-(2-carboxylate-2-6-diyl)) (PCE10)-doped hole-transport layer comprising spiro-OMeTAD, and a metal anode, and having a film thickness of 300 nm. USE - Perovskite solar cell. ADVANTAGE - The solar cell includes spiro-OMeTAD which increases short-circuit current, maintains open-circuit voltage, and improves photoelectric conversion efficiency. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is included for the preparation of the perovskite solar cell, which involves cleaning the substrate using detergent, acetone solution and deionized water, drying, performing UV treatment, spin coating electron transport layer comprising 2.67 wt.% tin oxide, annealing, isolating in a dust-free oxygen-free dry environment, spin coating perovskite precursor solution, annealing, spin coating 1mL 73.2 mg/mL spiro-OMeTAD solution on the perovskite active layer, adding 28.8 mu L tributyl phosphate, 17.5 mu L lithium-bis(trifluoromethanesulfonyl)imide, and 29 mu L 520 mg/mL Tris(2-(1H-pyrazol-1-yl)-4-tert-butylpyridine)-cobalt(III)tris(bis(trifluoromethylsulfonyl)imide), spin coating heterojunction, annealing, under high vacuum environment, evaporating metal cathode having a thickness of 100-200 nm on the hole transport layer, and, packaging.