• 专利标题:   Preparation of liquid-crystal polyester-grafted graphene oxide compound for reinforced-modified polymer matrix composite, involves dissolving 4,4'-bis(beta-hydroxybutyrate hexyloxy)biphenyl in N,N-dimethylformamide, and adding pyridine.
  • 专利号:   CN103965663-A, CN103965663-B
  • 发明人:   XU X, LU S, YU J, QI B, XIAO X, CENG C
  • 专利权人:   UNIV GUILIN TECHNOLOGY
  • 国际专利分类:   C08G063/672, C08G063/78, C08K003/04, C08K009/04, C09C001/46, C09C003/10
  • 专利详细信息:   CN103965663-A 06 Aug 2014 C09C-001/46 201470 Pages: 5 Chinese
  • 申请详细信息:   CN103965663-A CN10221362 25 May 2014
  • 优先权号:   CN10221362

▎ 摘  要

NOVELTY - Preparation of liquid-crystal polyester-grafted graphene oxide compound involves dissolving 3-7 g 4,4'-bis(( beta )-hydroxybutyrate hexyloxy)biphenyl in 50-80 ml N,N-dimethylformamide, adding 1 ml pyridine, heating, adding 2-5 g terephthaloyl chloride, reacting the resultant product, precipitating the resultant product, filtering, vacuum drying, dispersing 10-30 ml mixture of graphene oxide/N,N-dimethylformamide, adding 2 g catalyst, 0.15-0.5 g 4-dimethylaminopyridine and 1-3 g obtained liquid-crystal polyester, stirring, filtering the resultant product, washing and drying. USE - Preparation of liquid-crystal polyester-grafted graphene oxide compound used for reinforced-modified polymer matrix composite. ADVANTAGE - The method economically provides liquid-crystal polyester-grafted graphene oxide compound having excellent polymer interface compatibility, by simple process. DETAILED DESCRIPTION - Preparation of liquid-crystal polyester-grafted graphene oxide compound involves dissolving 3-7 g 4,4'-bis(( beta )-hydroxybutyrate hexyloxy)biphenyl in 50-80 ml N,N-dimethylformamide, adding 1 ml pyridine, heating the resultant product at 50-70 degrees C, then adding 2-5 g terephthaloyl chloride, reacting the resultant product at 50-70 degrees C for 6-10 hours, pouring the resultant product into distilled water, precipitating the resultant product, filtering, vacuum drying to obtain liquid-crystal polyester, ultrasonically dispersing 10-30 ml mixture of graphene oxide/N,N-dimethylformamide, adding 2 g catalyst, 0.15-0.5 g 4-dimethylaminopyridine and 1-3 g obtained liquid-crystal polyester, stirring the resultant product at 30-40 degrees C for 8-10 hours, filtering the resultant product, washing and drying. The catalyst is chosen from N,N-dicyclohexylcarbodiimide and N,N-diisopropylcarbodiimide.