• 专利标题:   Preparing composite wave absorbing material involves taking N,N-dimethylformamide and ethylene glycol in beaker, and mixing, weighing graphite oxide, sonicating, stirring, and adding nickel nitrate hexahydrate and zinc nitrate hexahydrate.
  • 专利号:   CN112897569-A, CN112897569-B
  • 发明人:   SHU R, DENG L, WU Y, LI X
  • 专利权人:   UNIV ANHUI SCI TECHNOLOGY
  • 国际专利分类:   B22F009/24, C01B032/00, C01B032/184, C01G009/02, C09K003/00
  • 专利详细信息:   CN112897569-A 04 Jun 2021 C01G-009/02 202158 Pages: 16 Chinese
  • 申请详细信息:   CN112897569-A CN10125667 29 Jan 2021
  • 优先权号:   CN10125667

▎ 摘  要

NOVELTY - Preparing a hollow nickel/zinc oxide/carbon/reduced graphene oxide composite absorbing material involves taking a 150ml beaker, adding 25ml N,N-dimethylformamide and 25ml ethylene glycol, and mixing well, weighing a certain amount respectively 30mg, 45mg, 60mg and 75mg graphite oxide, sonicating for 1 hour, stirring for 30 minutes, and then sonicating for 1 hour, and then adding 1mmol nickel nitrate hexahydrate, 1mmol zinc nitrate hexahydrate, and 1mmol terephthalene to graphene oxide dispersion, adding formic acid and 1.16g polyvinylpyrrolidone, and stirring vigorously for 2 hours. The mixed dispersion is transferred to a polytetrafluoroethylene lined autoclave with a volume of 100ml, and solvothermally reacted at 150 degrees C for 10 hours. The reaction mixture is cooled to room temperature, centrifugation is repeated, washed with dimethylformamide and absolute ethanol to collect the precipitate. The precipitate is put in a vacuum freeze dryer for drying for 24 hours. USE - Method for preparing a hollow nickel/zinc oxide/carbon/reduced graphene oxide composite absorbing material. ADVANTAGE - The method enables to prepare a hollow nickel/zinc oxide/carbon/reduced graphene oxide composite absorbing material with strong microwave absorption capacity, absorption frequency bandwidth and thin coating thickness in a simple and eco-friendly manner. DETAILED DESCRIPTION - Preparing a hollow nickel/zinc oxide/carbon/reduced graphene oxide composite absorbing material involves taking a 150ml beaker, adding 25ml N,N-dimethylformamide and 25ml ethylene glycol, and mixing well, weighing a certain amount respectively 30mg, 45mg, 60mg and 75mg graphite oxide, sonicating for 1 hour, stirring for 30 minutes, and then sonicating for 1 hour, and then adding 1mmol nickel nitrate hexahydrate, 1mmol zinc nitrate hexahydrate, and 1mmol terephthalene to graphene oxide dispersion, adding formic acid and 1.16g polyvinylpyrrolidone, and stirring vigorously for 2 hours. The mixed dispersion is transferred to a polytetrafluoroethylene lined autoclave with a volume of 100ml, and solvothermally reacted at 150 degrees C for 10 hours. The reaction mixture is cooled to room temperature, centrifugation is repeated, washed with dimethylformamide and absolute ethanol to collect the precipitate. The precipitate is put in a vacuum freeze dryer for drying for 24 hours. The high temperature heat treatment is carried out on the dried precipitate in a tube furnace with argon atmosphere at 600 degrees C at heating rate of 3 degrees C/minute for 5 hours. The final result is cooled to room temperature.