• 专利标题:   Shielding material useful for polypropylene-based thermoplastic cables comprises polypropylene, polyethylene octene co-elastomer, conductive carbon black, graphene, coupling agent, and antioxidant.
  • 专利号:   CN113150438-A
  • 发明人:   XUE Z, XU M, PENG Y, ZHAO L
  • 专利权人:   UNIV XIAN JIAOTONG
  • 国际专利分类:   C08J003/215, C08J003/22, C08K013/02, C08K003/04, C08L023/08, C08L023/12
  • 专利详细信息:   CN113150438-A 23 Jul 2021 C08L-023/12 202175 Pages: 10 Chinese
  • 申请详细信息:   CN113150438-A CN10383896 09 Apr 2021
  • 优先权号:   CN10383896

▎ 摘  要

NOVELTY - Shielding material comprises 50-70 pts. wt. polypropylene, 30-50 pts. wt. polyethylene octene co-elastomer, 10-20 pts. wt. conductive carbon black, 0.5-1.5 pts. wt. graphene, 0.5-1.5 pts. wt. coupling agent and 1-3 pts. wt. antioxidant. USE - The shielding material is useful for polypropylene-based thermoplastic cables. ADVANTAGE - The shielding material forms a synergistic effect with carbon black by adding graphene to improve electrical conductivity, graphene masterbatch made by ultrasonic dispersion and solution method, overcomes problem of serious stacking and agglomeration of graphene layers, and obtains better electrical and mechanical properties, and in case of meeting the electrical conductivity, and has a lower resistivity and positive temperature effect. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is also included for preparing polypropylene-based thermoplastic cable shielding material comprising (i) taking 50-70 pts. wt. polypropylene, 30-50 pts. wt. polyethylene octene co-elastomer, 10-20 pts. wt. conductive carbon black, 0.5-1.5 pts. wt. graphene, 0.5-1.5 pts. wt. coupling agent and 1-3 pts. wt. antioxidant, adding polyethylene octene co-elastomer into first solvent, stirring evenly at 100-120 degrees C, obtaining a polyolefin elastomerssolution, adding graphene into the second solvent, ultrasonically vibrating for 10-30 minutes, ultrasonic power is 150-300 w, and the graphene slurry after ultrasonic dispersion is obtained, (ii) adding the graphene slurry to the polyolefin elastomers solution and stirring evenly under heating to obtain a polyolefin elastomers/graphene mixed liquid, suction filtering polyolefin elastomers/graphene mixture to obtain a flocculent mixture, and drying to obtain a polyolefin elastomers /graphene masterbatch, (iii) mixing polypropylene, conductive carbon black, polyolefin elastomers/graphene masterbatch, adding antioxidant and coupling agent into extruder and melt blending at 180-210 degrees C, performing water-cooled pelletizing, drying and dehydration